Hydrocarboxylation of Terminal Alkenes in Supercritical Carbon Dioxide
作者： Clara Tortosa Estorach , Arantxa Orejón , Núria Ruiz , Anna M. Masdeu‐Bultó , Gábor Laurenczy
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摘要: The catalytic hydrocarboxylation of linear alkenes to carboxylic acids using supercritical carbon dioxide as a solvent was studied. High selectivities in have been obtained. best results were achieved when adding perfluorinated surfactant the reaction mixture (93% conversions and ca. 80% selectivity). Comparative multinuclear high-pressure NMR spectroscopic studies [D8]THF CO2 show formation Pd0 species.
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