Effective removal of Cr(VI) ions from synthetic solution using mixed biomasses: Kinetic, equilibrium and thermodynamic study

作者: P. Senthil Kumar , Sunita Varjani , P.R. Yaashikaa , A. Saravanan , S. Jeevanantham

DOI: 10.1016/J.JWPE.2020.101905

关键词:

摘要: Abstract Heavy metals are the prominent toxic pollutant extensively present in industrial waste. Due to its toxicity nature it should be removed from In this research, raw and pyrolysis assisted dragon fruit peel along with fungal biomass (Fusarium subglutinans) was utilized as a mixed adsorbent for removal of Cr(VI) ions aqueous phase. FTIR, SEM, EDX analyses were used characterize synthesized biomasses subglutinans – RDFP Fusarium - PADFP). Batch adsorption tests reveal that optimum conditions effective onto (pH = 4.0; dosage =6.0 g/L RDFP, 3.5 g/L PADFP; temperature =30 °C; ion concentration =25 mg/L; equilibrium time =60 min). The data contact best fitted Langmiur Pseudo-first-order model, respectively. monolayer capacities found 11.0 mg/g 16.52 mg/g PADFP. Thermodynamic parameters demonstrated favorable at low temperatures exothermic process. Overall results exposed had superior capacity water/wastewater.

参考文章(77)
M Ghaedi, S Hajjati, Z Mahmudi, I Tyagi, Shilpi Agarwal, A Maity, VK Gupta, None, Modeling of competitive ultrasonic assisted removal of the dyes – Methylene blue and Safranin-O using Fe3O4 nanoparticles Chemical Engineering Journal. ,vol. 268, pp. 28- 37 ,(2015) , 10.1016/J.CEJ.2014.12.090
Shaili Srivastava, Indu Shekhar Thakur, Isolation and process parameter optimization of Aspergillus sp. for removal of chromium from tannery effluent. Bioresource Technology. ,vol. 97, pp. 1167- 1173 ,(2006) , 10.1016/J.BIORTECH.2005.05.012
Amit Bhatnagar, Mika Sillanpää, Anna Witek-Krowiak, Agricultural waste peels as versatile biomass for water purification – A review Chemical Engineering Journal. ,vol. 270, pp. 244- 271 ,(2015) , 10.1016/J.CEJ.2015.01.135
Charles R. Myers, The effects of chromium(VI) on the thioredoxin system: Implications for redox regulation Free Radical Biology and Medicine. ,vol. 52, pp. 2091- 2107 ,(2012) , 10.1016/J.FREERADBIOMED.2012.03.013
Robert Sips, On the Structure of a Catalyst Surface The Journal of Chemical Physics. ,vol. 16, pp. 490- 495 ,(1948) , 10.1063/1.1746922
József Tóth, Calculation of the BET-Compatible Surface Area from Any Type I Isotherms Measured above the Critical Temperature. joint international conference on information sciences. ,vol. 225, pp. 378- 383 ,(1999) , 10.1006/JCIS.2000.6723
A.H.M.G. Hyder, Shamim A. Begum, Nosa O. Egiebor, Adsorption isotherm and kinetic studies of hexavalent chromium removal from aqueous solution onto bone char Journal of environmental chemical engineering. ,vol. 3, pp. 1329- 1336 ,(2015) , 10.1016/J.JECE.2014.12.005
P. Senthil Kumar, S. Ramalingam, C. Senthamarai, M. Niranjanaa, P. Vijayalakshmi, S. Sivanesan, Adsorption of dye from aqueous solution by cashew nut shell: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions Desalination. ,vol. 261, pp. 52- 60 ,(2010) , 10.1016/J.DESAL.2010.05.032
M. J. D. Low, Kinetics of Chemisorption of Gases on Solids. Chemical Reviews. ,vol. 60, pp. 267- 312 ,(1960) , 10.1021/CR60205A003