Effect of roughness geometry on wetting and dewetting of rough PDMS surfaces.

作者: Mandakini Kanungo , Srinivas Mettu , Kock-Yee Law , Susan Daniel

DOI: 10.1021/LA404343N

关键词:

摘要: Rough PDMS surfaces comprising 3 μm hemispherical bumps and cavities with pitches ranging from 4.5 to 96 have been fabricated by photolithographic molding techniques. Their wetting dewetting behavior water was studied as model for print used in additive manufacturing printed electronics. A smooth surface control. For a given pitch, both bumpy cavity exhibit similar static contact angles, which increase the roughness ratio increases. Notably, observed angles are shown be consistently larger than calculated Wenzel attributable pinning of droplets into metastable states. Optical microscopy reveals that lines on distorted microtextures, at lead edges cavities. Vibration sessile smooth, bumpy, results same angle, 110°-124° ∼91°. The suggest all three stable states after vibration pin area rough surfaces. This conclusion is supported visual inspection before vibration. importance location rather energy angle discussed. droplet examining receding motion line evaporating very dilute rhodamine dye solution these reveal dragged it recedes, whereas dragging not visible drag created toward process also velocity-dependent advancing experiments.

参考文章(52)
G.E.P Elliott, A.C Riddiford, Dynamic contact angles Journal of Colloid and Interface Science. ,vol. 23, pp. 389- 398 ,(1967) , 10.1016/0021-9797(67)90183-X
Robert D. Deegan, Olgica Bakajin, Todd F. Dupont, Greb Huber, Sidney R. Nagel, Thomas A. Witten, Capillary flow as the cause of ring stains from dried liquid drops Nature. ,vol. 389, pp. 827- 829 ,(1997) , 10.1038/39827
Lichao Gao, Thomas J. McCarthy, Wetting 101 degrees. Langmuir. ,vol. 25, pp. 14105- 14115 ,(2009) , 10.1021/LA902206C
Robert A. Hayes, Andrew C. Robinson, John Ralston, A Wilhelmy Technique for the Rapid Assessment of Solid Wetting Dynamics Langmuir. ,vol. 10, pp. 2850- 2852 ,(1994) , 10.1021/LA00020A057
Adam C. Siegel, Scott T. Phillips, Michael D. Dickey, Nanshu Lu, Zhigang Suo, George M. Whitesides, Foldable Printed Circuit Boards on Paper Substrates Advanced Functional Materials. ,vol. 20, pp. 28- 35 ,(2010) , 10.1002/ADFM.200901363
Robert N. Wenzel, RESISTANCE OF SOLID SURFACES TO WETTING BY WATER Industrial & Engineering Chemistry. ,vol. 28, pp. 988- 994 ,(1936) , 10.1021/IE50320A024
M. J. de Ruijter, J. De Coninck, T. D. Blake, A. Clarke, A. Rankin, Contact angle relaxation during the spreading of partially wetting drops Langmuir. ,vol. 13, pp. 7293- 7298 ,(1997) , 10.1021/LA970825V
Jungchul Kim, Myoung-Woon Moon, Kwang-Ryeol Lee, L. Mahadevan, Ho-Young Kim, Hydrodynamics of writing with ink. Physical Review Letters. ,vol. 107, pp. 264501- 264501 ,(2011) , 10.1103/PHYSREVLETT.107.264501
Jaakko V. I. Timonen, Mika Latikka, Olli Ikkala, Robin H. A. Ras, Free-decay and resonant methods for investigating the fundamental limit of superhydrophobicity Nature Communications. ,vol. 4, pp. 2398- ,(2013) , 10.1038/NCOMMS3398