Infrared rotation and vibration-rotation bands of endohedral fullerene complexes. Absorption spectrum of Li+@C60 in the range 1-1000 cm-1
作者： C.G. Joslin , J. Yang , C.G. Gray , S. Goldman , J.D. Poll
DOI: 10.1016/0009-2614(93)80081-Y
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摘要: Abstract The infrared spectrum of the endohedral metallofullerene Li + @C 60 is calculated. Vibrational and rotational motion charged inclusion leads to emission absorption radiation. Our calculations assume this governed by intramolecular “reflected Morse” potential Dunlap, Ballester Schmidt. predicted pure rotation band peaks near 40 cm −1 . fundamental vibration—rotation at 350 exhibits unusual band-head structure. Both bands are intense. first overtone 700 also studied. Rotational structure well resolved in all three bands; room temperature, hot contribute significantly.
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H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl, R. E. Smalley, C 60 : Buckminsterfullerene Nature. ,vol. 318, pp. 162- 163 ,(1985) , 10.1038/318162A0
B. I. Dunlap, J. L. Ballester, P. P. Schmidt, Interactions between fullerene (C60) and endohedral alkali atoms The Journal of Physical Chemistry. ,vol. 96, pp. 9781- 9787 ,(1992) , 10.1021/J100203A038
Jerzy Cioslowski, Asiri Nanayakkara, Endohedral effect in inclusion complexes of the C60 cluster Journal of Chemical Physics. ,vol. 96, pp. 8354- 8362 ,(1992) , 10.1063/1.462288
Jerzy Cioslowski, Endohedral chemistry: electronic structures of molecules trapped inside the C60 cage Journal of the American Chemical Society. ,vol. 113, pp. 4139- 4141 ,(1991) , 10.1021/JA00011A013
Zhimin Wan, James F. Christian, Scott L. Anderson, Ne++C60: Collision energy and impact parameter dependence for endohedral complex formation, fragmentation, and charge transfer Journal of Chemical Physics. ,vol. 96, pp. 3344- 3347 ,(1992) , 10.1063/1.461931
Mark M. Ross, John H. Callahan, Formation and characterization of carbon mol.-helium (C60He+) The Journal of Physical Chemistry. ,vol. 95, pp. 5720- 5723 ,(1991) , 10.1021/J100168A004
P. P. Schmidt, B. I. Dunlap, C. T. White, Endohedral vibrations of sodium(1+) in fullerene (C60) The Journal of Physical Chemistry. ,vol. 95, pp. 10537- 10541 ,(1991) , 10.1021/J100179A005
J. M. HAWKINS, A. MEYER, T. A. LEWIS, S. LOREN, F. J. HOLLANDER, Crystal structure of osmylated c60: confirmation of the soccer ball framework. Science. ,vol. 252, pp. 312- 313 ,(1991) , 10.1126/SCIENCE.252.5003.312
P.W. Fowler, P. Lazzeretti, R. Zanasi, Electric and magnetic properties of the aromatic sixty-carbon cage Chemical Physics Letters. ,vol. 165, pp. 79- 86 ,(1990) , 10.1016/0009-2614(90)87015-J
Marcos M. Alvarez, E. G. Gillan, Karoly Holczer, Richard B. Kaner, K. S. Min, Robert L. Whetten, Lanthanum carbide (La2C80): a soluble dimetallofullerene The Journal of Physical Chemistry. ,vol. 95, pp. 10561- 10563 ,(1991) , 10.1021/J100179A014