Synthesis and pharmacology of 8-amino-3-(cyclopropylmethyl)-1,2,3,4,5,6-hexahydro-cis-6,11-dimethyl-2,6-methano-3-benzazocine and related compounds.
作者： Mark P. Wentland , Noel F. Albertson , Anne K. Pierson
DOI: 10.1021/JM00175A013
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摘要: The little compound 1a has been prepared and was found to be a strong, orally active agonist with narcotic--antagonist properties. by two independent routes: (1) nitration of volazocine subsequent reduction (b) sequence involving dissolving metal cyclazocine methyl ether, followed oximination Semmler--Wolff rearrangement. Several analogues were tested.
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