摘要: Abstract A covalent network of polymer can imbibe a solvent to form gel. In cavity on the surface gel, capillary force may suck out gel pure liquid phase. We show that such osmocapillary phase separation occurs when capillarity balances osmosis, and diffusion in prevails over condensation from vapor. Osmocapillary occur even is isolated vapor, or nonvolatile. relate phenomena practical significance, including wettability gels, transparency bridge at tip an atomic microscope, adhesion between another substance, morphology production tight oil.
harvard.edu
sci-hub.se 参考文章(35)
David J. Beebe, Jeffrey S. Moore, Joseph M. Bauer, Qing Yu, Robin H. Liu, Chelladurai Devadoss, Byung-Ho Jo, Functional hydrogel structures for autonomous flow control inside microfluidic channels Nature. ,vol. 404, pp. 588- 590 ,(2000) , 10.1038/35007047
Evan Hohlfeld, L. Mahadevan, Unfolding the sulcus. Physical Review Letters. ,vol. 106, pp. 105702- ,(2011) , 10.1103/PHYSREVLETT.106.105702
James E. McDonald, Homogeneous Nucleation of Vapor Condensation. II. Kinetic Aspects American Journal of Physics. ,vol. 31, pp. 31- 41 ,(1963) , 10.1119/1.1969234
Shengqiang Cai, Yucun Lou, Partha Ganguly, Agathe Robisson, Zhigang Suo, Force generated by a swelling elastomer subject to constraint Journal of Applied Physics. ,vol. 107, pp. 103535- ,(2010) , 10.1063/1.3428461
Roya Maboudian, Roger T Howe, Critical Review: Adhesion in surface micromechanical structures Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures. ,vol. 15, pp. 1- 20 ,(1997) , 10.1116/1.589247
David H Gracias, Joe Tien, Tricia L Breen, Carey Hsu, George M Whitesides, Forming electrical networks in three dimensions by self-assembly Science. ,vol. 289, pp. 1170- 1172 ,(2000) , 10.1126/SCIENCE.289.5482.1170
B. Pokroy, S. H. Kang, L. Mahadevan, J. Aizenberg, Self-organization of a mesoscale bristle into ordered, hierarchical helical assemblies. Science. ,vol. 323, pp. 237- 240 ,(2009) , 10.1126/SCIENCE.1165607
Enrique Sahagún, Pedro García-Mochales, GM Sacha, Juan Jose Sáenz, Energy Dissipation due to Capillary Interactions: Hydrophobicity Maps in Force Microscopy Physical Review Letters. ,vol. 98, pp. 176106- ,(2007) , 10.1103/PHYSREVLETT.98.176106
Maciej A Zwieniecki, Peter J Melcher, N Michele Holbrook, Hydrogel Control of Xylem Hydraulic Resistance in Plants Science. ,vol. 291, pp. 1059- 1062 ,(2001) , 10.1126/SCIENCE.1057175
William W. Mullins, Flattening of a Nearly Plane Solid Surface due to Capillarity Journal of Applied Physics. ,vol. 30, pp. 77- 83 ,(1959) , 10.1063/1.1734979