Quadrupole Coupling of Solid Cyanogen Chloride

作者: P. A. Casabella , P. J. Bray

DOI: 10.1063/1.1744364

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摘要: The nuclear quadrupole resonances of N14 and Cl35 have been observed in solid ClCN. In the course study a detailed was made shape negative wings which occur when Zeeman modulation phase sensitive detection are used. these can reveal whether two due to nonequivalent positions nuclei, or one position with nonzero asymmetry parameter. A theoretical expression has derived for agrees experimental results. coupling constants nuclei interpreted terms set hybrid structures.

参考文章(9)
H. Kr�ger, Beiträge zur Untersuchung der reinen Kernquadrupolspektren in Kristallen European Physical Journal. ,vol. 130, pp. 371- 384 ,(1951) , 10.1007/BF01340173
A. L. Schawlow, Nuclear Quadrupole Resonances in Solid Bromine in Iodine Compounds The Journal of Chemical Physics. ,vol. 22, pp. 1211- 1214 ,(1954) , 10.1063/1.1740335
R. Bersohn, Double‐Bond Character of Conjugated Carbon‐Chlorine Bonds Journal of Chemical Physics. ,vol. 22, pp. 2078- 2083 ,(1954) , 10.1063/1.1739996
H. G. Dehmelt, Nuclear Quadrupole Resonance American Journal of Physics. ,vol. 22, pp. 110- 120 ,(1954) , 10.1119/1.1933644
P. J. Bray, R. G. Barnes, Estimates of Hammett's Sigma Values from Quadrupole Resonance Studies The Journal of Chemical Physics. ,vol. 27, pp. 551- 560 ,(1957) , 10.1063/1.1743767
S. Geller, A. L. Schawlow, Crystal Structure and Quadrupole Coupling of Cyanogen Bromide, BrCN Journal of Chemical Physics. ,vol. 23, pp. 779- 783 ,(1955) , 10.1063/1.1742121
R. B. Heiart, G. B. Carpenter, THE CRYSTAL STRUCTURE OF CYANOGEN CHLORIDE Acta Crystallographica. ,vol. 9, pp. 889- 895 ,(1955) , 10.1107/S0365110X56002527
G. D. Watkins, R. V. Pound, The Pure Nuclear Electric Quadrupole Resonance ofN14in Three Molecular Solids Physical Review. ,vol. 85, pp. 1062- 1062 ,(1952) , 10.1103/PHYSREV.85.1062
Hans-Georg Dehmelt, Kernquadrupolfrequenzen in kristallinen Jodverbindungen Naturwissenschaften. ,vol. 37, pp. 398- 398 ,(1950) , 10.1007/BF00738365