Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)
作者： Rachid Touzani , Michael Haibach , Agnieszka J. Nawara-Hultzsch , Sghir El Kadiri , Thomas J. Emge
DOI: 10.1016/J.POLY.2011.06.038
关键词:
摘要: Abstract The complexation of the simple 1-hydroxymethyl-3,5-dimethylpyrazole (HL) ligand with Fe and Ni salts leads to interesting polynuclear complexes in good yield. X-ray diffraction reveals that resulting (μ4-L)4Ni4Cl4(H2O)4 (μ2-L)4(μ3-L)2Fe8Cl16(μ4-O)6 adopt cubane-type open-cubane-type structures solid state.
elsevier.com
sci-hub.se 参考文章(56)
Nobumasa Kitajima, William B. Tolman, Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl)borate Ligands: Organometallic and Bioinorganic Perspectives Progress in Inorganic Chemistry. pp. 419- 531 ,(2007) , 10.1002/9780470166444.CH5
Patrick Gamez, Peter G. Aubel, Willem L. Driessen, Jan Reedijk, Homogeneous bio-inspired copper-catalyzed oxidation reactions Chemical Society Reviews. ,vol. 30, pp. 376- 385 ,(2001) , 10.1039/B104827A
Juan M. Clemente-Juan, Christine Mackiewicz, Marc Verelst, Françoise Dahan, Azzedine Bousseksou, Yiannis Sanakis, Jean-Pierre Tuchagues, Synthesis, Structure, and Magnetic Properties of Tetranuclear Cubane-like and Chain-like Iron(II) Complexes Based on the N4O Pentadentate Dinucleating Ligand 1,5-Bis[(2-pyridylmethyl)amino]pentan-3-ol Inorganic Chemistry. ,vol. 41, pp. 1478- 1491 ,(2002) , 10.1021/IC010787+
Waldemar Mazurek, Brendan J. Kennedy, Keith S. Murray, Maxwell J. O'Connor, John R. Rodgers, Michael R. Snow, Anthony G. Wedd, Peter Zwack, Magnetic interactions in metal complexes of binucleating ligands. 2. Synthesis and properties of binuclear copper(II) compounds containing exogenous ligands that bridge through two atoms. Crystal and molecular structure of a binuclear .mu.-pyrazolato-N,N'-bridged dicopper(II) complex of 1,3-bis(salicylideneamino)propan-2-ol Inorganic Chemistry. ,vol. 24, pp. 3258- 3264 ,(1985) , 10.1021/IC00214A033
V. Hanot, T. Robert, SYNTHESIS AND PRELIMINARY STUDY OF CU(II) AND PD(II) COMPLEXES WITH A NEW CHELATING BIS(TRIAZOLYL)TRIAZENIDO LIGAND Journal of Coordination Chemistry. ,vol. 32, pp. 349- 352 ,(1994) , 10.1080/00958979408024254
Syunsuke Uozumi, Hideki Furutachi, Masaaki Ohba, Hisashi Ōkawa, David E. Fenton, Kenji Shindo, Susumu Murata, David J. Kitko, Dinuclear Nickel(II) Complexes of an Unsymmetric “End-Off” Compartmental Ligand: Conversion of Urea into Cyanate at a Dinuclear Nickel Core Inorganic Chemistry. ,vol. 37, pp. 6281- 6287 ,(1998) , 10.1021/IC9807689
Jon Lawrence, En-Che Yang, Rachel Edwards, Marilyn M. Olmstead, Chris Ramsey, Naresh S. Dalal, Peter K. Gantzel, Stephen Hill, David N. Hendrickson, Disorder and intermolecular interactions in a family of tetranuclear Ni(II) complexes probed by high-frequency electron paramagnetic resonance. Inorganic Chemistry. ,vol. 47, pp. 1965- 1974 ,(2008) , 10.1021/IC701416W
En-Che Yang, Wolfgang Wernsdorfer, Lev N. Zakharov, Yoshitomo Karaki, Akira Yamaguchi, Rose M. Isidro, Guo-Di Lu, Samuel A. Wilson, Arnold L. Rheingold, Hidehiko Ishimoto, David N. Hendrickson, Fast magnetization tunneling in tetranickel(II) single-molecule magnets. Inorganic Chemistry. ,vol. 45, pp. 529- 546 ,(2006) , 10.1021/IC050093R
Sarah Cromie, Vickie McKee, Frédéric Launay, Site-selectivity in a heterotetranuclear macrocyclic complex. Chemical Communications. pp. 1918- 1919 ,(2001) , 10.1039/B106340P
Yi-Chian Chou, Shu-Fei Huang, Rajesh Koner, Gene-Hsiang Lee, Yu Wang, Sasankasekhar Mohanta, Ho-Hsiang Wei, Ferromagnetic exchange in two dicopper(II) complexes using a mu-alkoxo-mu-7-azaindolate bridge. Inorganic Chemistry. ,vol. 43, pp. 2759- 2761 ,(2004) , 10.1021/IC035322T