Removal of amoxicillin from simulated hospital effluents by adsorption using activated carbons prepared from capsules of cashew of Para

作者: Diana Ramos Lima , Eder C Lima , Cibele S Umpierres , Pascal Silas Thue , Ghadir A El-Chaghaby

DOI: 10.1007/S11356-019-04994-6

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摘要: High-surface-area activated carbons were prepared from an agroindustrial residue, Bertholletia excelsa capsules known as of Para cashew (CCP), that utilized for removing amoxicillin aqueous effluents. The with the proportion CCP:ZnCl2 1:1, and this mixture was pyrolyzed at 600 (CCP-600) 700 °C (CCP700). CCP.600 CCP.700 characterized by CHN/O elemental analysis, hydrophobic/hydrophilic ratio, FTIR, TGA, Boehm titration, total pore volume, surface area. These analyses show adsorbents have different polar groups, which confers a hydrophilic surface. presented area volume 1457 m2 g−1 0.275 cm3 g−1 (CCP.600) 1419 m2 g−1 0.285 cm3 g−1 (CCP.700). chemical physical properties very close, indicating pyrolysis temperature does not bring relevant differences in these adsorbents. adsorption data kinetics equilibrium successfully adjusted to Avrami fractional-order Liu isotherm model. use treatment simulated hospital effluents, containing organic inorganic compounds, showed excellent removals (up 98.04% 98.60% CCP.700).

参考文章(52)
Matthias Thommes, Katsumi Kaneko, Alexander V. Neimark, James P. Olivier, Francisco Rodriguez-Reinoso, Jean Rouquerol, Kenneth S.W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Pure and Applied Chemistry. ,vol. 87, pp. 1051- 1069 ,(2015) , 10.1515/PAC-2014-1117
Joaquim L. Faria, Olga C. Nunes, M. Fernando R. Pereira, Adrián M.T. Silva, Nuno F.F. Moreira, Carla A. Orge, Ana R. Ribeiro, Fast mineralization and detoxification of amoxicillin and diclofenac by photocatalytic ozonation and application to an urban wastewater Water Research. ,vol. 87, pp. 87- 96 ,(2015) , 10.1016/J.WATRES.2015.08.059
Timothy A. Nieman, Douglas A. Skoog, F. James Holler, Principles of Instrumental Analysis ,(1971)
Lizie DT Prola, Fernando M Machado, Carlos P Bergmann, Felipe E de Souza, Caline R Gally, Eder C Lima, Matthew A Adebayo, Silvio LP Dias, Tatiana Calvete, None, Adsorption of Direct Blue 53 dye from aqueous solutions by multi-walled carbon nanotubes and activated carbon. Journal of Environmental Management. ,vol. 130, pp. 166- 175 ,(2013) , 10.1016/J.JENVMAN.2013.09.003
Éder C Lima, Francisco J Krug, Joaquim A Nóbrega, Ana Rita A Nogueira, None, Determination of ytterbium in animal faeces by tungsten coil electrothermal atomic absorption spectrometry Talanta. ,vol. 47, pp. 613- 623 ,(1998) , 10.1016/S0039-9140(98)00087-3
�der C. Lima, Fernando Barbosa Jr., Francisco J. Krug, Uelinton Guaita, Tungsten-rhodium permanent chemical modifier for lead determination in digests of biological materials and sediments by electrothermal atomic absorption spectrometry Journal of Analytical Atomic Spectrometry. ,vol. 14, pp. 1601- 1605 ,(1999) , 10.1039/A903270C
Rajajeyaganthan Ramanathan, Daniel E. Weibel, Novel liquid–solid adhesion superhydrophobic surface fabricated using titanium dioxide and trimethoxypropyl silane Applied Surface Science. ,vol. 258, pp. 7950- 7955 ,(2012) , 10.1016/J.APSUSC.2012.04.140
Sarah L. Goertzen, Kim D. Thériault, Alicia M. Oickle, Anthony C. Tarasuk, Heather A. Andreas, Standardization of the Boehm titration. Part I. CO2 expulsion and endpoint determination Carbon. ,vol. 48, pp. 1252- 1261 ,(2010) , 10.1016/J.CARBON.2009.11.050