Dynamics of a Complex Multilayer Polymer Network: Mechanical Relaxation and Energy Transfer.

摘要: In this paper, we focus on the mechanical relaxation of a multilayer polymer network built by connecting identical layers that have, as underlying topologies, dual Sierpinski gasket and regular dendrimer. Additionally, analyze dynamics dipolar energy transfer over system chromophores arranged in form network. Both dynamical processes are studied framework generalized Gaussian structure (GSS) model. We develop method whereby whole eigenvalue spectrum connectivity matrix can be determined iteratively, thereby rendering possible analysis networks consisting large number layers. This fact allows us to study detail crossover from layer-like behavior chain-like behavior. Remarkably, highlight existence two bulk-like behaviors. The theoretical findings with respect decomposition intermediate domain quantities, well behavior, supported experimental results.