High resolution XPS studies of Se chemistry of a Cu(In, Ga)Se2 surface

作者: B Canava , J Vigneron , A Etcheberry , J.F Guillemoles , D Lincot

DOI: 10.1016/S0169-4332(02)00186-1

关键词:

摘要: Abstract Chemistry of co-evaporated Cu(In, Ga)Se2 (CIGS) surfaces submitted or not to chemical treatments was investigated by high resolution XPS. The surface analysis allowed us compare the composition with bulk one as a function treatments. We also studied too several standard compounds Cu2−xSe, In2Se3, ZnSe, Se0 and CdSe. A Se XPS signal specific CIGS identified. In this paper, we present detailed study in show different spectroscopic contributions can be separated using standards information. Then, discuss origin these signals implications for device processing.

参考文章(11)
M. Sander, W. Jaegermann, H. J. Lewerenz, Site-specific surface interaction of adsorbed water and halogens on copper indium selenide (CuInSe2) surfaces The Journal of Physical Chemistry. ,vol. 96, pp. 782- 790 ,(1992) , 10.1021/J100181A048
J.C.W Folmer, F Jellinek, The valence of copper in sulphides and selenides: An X-ray photoelectron spectroscopy study Journal of the Less Common Metals. ,vol. 76, pp. 153- 162 ,(1980) , 10.1016/0022-5088(80)90019-3
Miguel A. Contreras, Brian Egaas, K. Ramanathan, J. Hiltner, A. Swartzlander, F. Hasoon, Rommel Noufi, Progress toward 20% efficiency in Cu(In,Ga)Se2 polycrystalline thin‐film solar cells Progress in Photovoltaics. ,vol. 7, pp. 311- 316 ,(1999) , 10.1002/(SICI)1099-159X(199907/08)7:4<311::AID-PIP274>3.0.CO;2-G
D Schmid, M Ruckh, H.W Schock, Photoemission studies on Cu(In, Ga)Se2 thin films and related binary selenides Applied Surface Science. ,vol. 103, pp. 409- 429 ,(1996) , 10.1016/S0169-4332(96)00099-2
C. Heske, D. Eich, R. Fink, E. Umbach, T. van Buuren, C. Bostedt, L. J. Terminello, S. Kakar, M. M. Grush, T. A. Callcott, F. J. Himpsel, D. L. Ederer, R. C. C. Perera, W. Riedl, F. Karg, Observation of intermixing at the buried CdS/Cu(In, Ga)Se2 thin film solar cell heterojunction Applied Physics Letters. ,vol. 74, pp. 1451- 1453 ,(1999) , 10.1063/1.123578
M Powalla, B Dimmler, Scaling up issues of CIGS solar cells Thin Solid Films. ,vol. 361, pp. 540- 546 ,(2000) , 10.1016/S0040-6090(99)00849-4
B. Dimmler, H. W. Schock, Scaling-up of CIS technology for thin-film solar modules Progress in Photovoltaics. ,vol. 4, pp. 425- 433 ,(1996) , 10.1002/(SICI)1099-159X(199611/12)4:6<425::AID-PIP153>3.0.CO;2-Y
T. K. Bandyopadhyay, S. B. Chakraborty, S. R. Chaudhuri, Effect of surface treatment on the photoanodic behaviour of thin film n-CdSe Physica Status Solidi (a). ,vol. 108, pp. K119- K123 ,(1988) , 10.1002/PSSA.2211080249