Determination of microscopic parameters for nonresonant energy-transfer processes in rare-earth-doped crystals

作者: L. V. G. Tarelho , L. Gomes , I. M. Ranieri

DOI: 10.1103/PHYSREVB.56.14344

关键词:

摘要: A method for estimating the microscopic probability rate of phonon-assisted energy transfer between rareearth (31) ions in solids was developed based on Dexter’s theory transfer. The proposed this paper enables one to calculate overlap integral from fundamental cross-section spectra nonresonant involving a multiphonon generation both donor and acceptor sites. translation emission spectrum towards absorption scaled with N-phonon represents m-phonon band which performs acceptor. nonvanishing 10 – times smaller than resonant case is found. assisting considered due combined mechanism creation annihilation phonons. participation each phonon process determined. This used investigate Tm(F4)→Ho(I7),Er(I13/2)→@Ho~I7),Tm(F4)] direct transfers LiYF4 crystals, as well back transfers. @S0163-1829~97!00545-6#

参考文章(11)
L. Gomes, L. C. Courrol, L. V. G. Tarelho, I. M. Ranieri, Cross-relaxation process between +3 rare-earth ions in LiYF4 crystals. Physical Review B. ,vol. 54, pp. 3825- 3829 ,(1996) , 10.1103/PHYSREVB.54.3825
D. L. Dexter, A Theory of Sensitized Luminescence in Solids The Journal of Chemical Physics. ,vol. 21, pp. 836- 850 ,(1953) , 10.1063/1.1699044
G.M. Renfro, J.C. Windscheif, W.A. Sibley, R.F. Belt, Optical transitions of Pr3+ and Er3+ ions in LiYF4☆ Journal of Luminescence. ,vol. 22, pp. 51- 68 ,(1980) , 10.1016/0022-2313(80)90045-9
François Auzel, Yihong Chen, Photon avalanche luminescence of Er3+ ions in LiYF4 crystal Journal of Luminescence. ,vol. 65, pp. 45- 56 ,(1995) , 10.1016/0022-2313(94)00071-J
D. E. McCumber, Einstein Relations Connecting Broadband Emission and Absorption Spectra Physical Review. ,vol. 136, pp. A954- A957 ,(1964) , 10.1103/PHYSREV.136.A954
S A Payne, L K Smith, W L Kway, J B Tassano, W F Krupke, The mechanism of Tm to Ho energy transfer in LiYF4 Journal of Physics: Condensed Matter. ,vol. 4, pp. 8525- 8542 ,(1992) , 10.1088/0953-8984/4/44/014