Synthesis, Crystal Structure and Hirshfeld Surfaces of the N-(bis(benzylamino)phosphoryl)-4-Methylbenzenesulfonamide Polymeric tetrakis -Complex {Na[Yb( L ) 4 ( i PrOH )]} n

摘要: Lanthanide containing polymer chain of title compound {Na[Yb(L)4(iPrOH)]}n is formed by alternating complex anions and sodium cations. The anion composed four deprotonated bidentate chelate ligands sulfonylamidophosphate type N-(bis(benzylamino)phosphoryl)-4-methylbenzenesulfonamide (L−) coordinated to the Yb(III) ion via O atoms belonging sulfonyl phosphoryl groups. coordination polyhedron ytterbium has a slightly distorted triangular dodecahedron conformation, TDD-8, D2d. Na+ cation atoms, NaO4 polyhedra shape intermediate between axially vacant trigonal bipyramid C3v tetrahedron Td. Single-crystal X-ray diffraction studies show that one 2-propanol molecule hydrogen-bonded sulphonyl oxygen ligands. Also extensive network hydrogen bonding interactions aromatic rings both in structural unit chains were detected. They investigated analysis Hirshfeld surfaces fingerprint plots. correlations structure parameters obtained physico-chemical properties investigated. New tetrakis-complex was synthesized characterized crystallography. Structural packaging characteristics surfaces.