Resistance of the Polypyrrole/Polyimide Composite by Electrochemical Impedance Spectroscopy

作者: Kirill L. Levine , Jude O. Iroh

DOI: 10.1023/B:JOPO.0000027364.19392.D2

关键词:

摘要: Electrically conducting polymers are promising for applications in polymer based charge storage devices and membrane applications. Composing polypyrrole with polyimide improves mechanical properties of affects the electrochemical composite. In this paper resistance to ion flow pure polypyrrole/polyimide composite were studied by impedance spectroscopy, comparatively, as a function applied potentials amount polypyrrole. Electron scanning microscopy surface mapping used characterization. Observed behavior was explained electroactivity components Conclusions about effect on structure made.

参考文章(8)
Yu. N. Sazanov, Applied significance of polyimides Russian Journal of Applied Chemistry. ,vol. 74, pp. 1253- 1269 ,(2001) , 10.1023/A:1013768725369
I. Okazaki, H. Ohya, S.I. Semenova, M. Aihara, Y. Negishi, Study on molecular weight cut-off performance of asymmetric aromatic polyimide membrane “Effect of the additive agents” Journal of Membrane Science. ,vol. 141, pp. 277- 282 ,(1998) , 10.1016/S0376-7388(97)00317-7
Jude O. Iroh, Kirill Levine, Capacitance of the polypyrrole/polyimide composite by electrochemical impedance spectroscopy Journal of Power Sources. ,vol. 117, pp. 267- 272 ,(2003) , 10.1016/S0378-7753(03)00356-2
Elena Vallejo, Gérald Pourcelly, Claude Gavach, Régis Mercier, Michel Pineri, Sulfonated polyimides as proton conductor exchange membranes. Physicochemical properties and separation H+/Mz+ by electrodialysis comparison with a perfluorosulfonic membrane Journal of Membrane Science. ,vol. 160, pp. 127- 137 ,(1999) , 10.1016/S0376-7388(99)00070-8
H Kawakami, K Nakajima, S Nagaoka, Gas separation characteristics of isomeric polyimide membrane prepared under shear stress Journal of Membrane Science. ,vol. 211, pp. 291- 298 ,(2003) , 10.1016/S0376-7388(02)00428-3
Miroslav Marek, Eduard Brynda, Milan Houska, Jan Schauer, Vladimír Hynek, Milan Šípek, Ultra-thin polyimide film as a gas-separation layer for composite membranes Polymer. ,vol. 37, pp. 2577- 2579 ,(1996) , 10.1016/0032-3861(96)85375-4
G.A. Polotskaya, T.A. Kostereva, G.K. Elyashevich, Gas transport properties and structural order of poly(4,4′-oxydiphenylene piromelliteimide) in composite membranes Separation and Purification Technology. ,vol. 14, pp. 13- 18 ,(1998) , 10.1016/S1383-5866(98)00055-0