Specific functionalization on the surface of dendrimers
作者： Michael Slany , Anne-Marie Caminade , Jean Pierre Majoral
DOI: 10.1016/S0040-4039(96)02123-5
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摘要: A specific monosubstitution on each P(X)(NHCH2CHCH2)2 terminal group (X = O, S) of phosphorus dendrimers is described, from generation 1 to 7. This reaction allows isolate compounds which possess simultaneously up 192 phosphine, NH and 384 allyl groups. Preliminary experiments show that these functionalized are able complex transition metals such as iron tungsten.
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