Techno-economic comparison of reverse water gas shift reaction to steam and dry methane reforming reactions for syngas production

作者: Ebrahim Rezaei , Stephen Dzuryk

DOI: 10.1016/J.CHERD.2019.02.005

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摘要: Abstract This work evaluates the economics of syngas production processes by reverse water gas shift (rWGS) reaction against dry methane reforming (DMR) and its combination with steam (SMR-DMR). The DMR SMR-DMR show lower total annual costs comparing to rWGS process for H2/CO ratio 1 2, respectively. Breakeven analysis has been performed on price H2, natural gas, CO2 tax rate. At a H2 $1/kg, is comparable when rate are $0.53/m3 (STP) $44/1000 kg, For be as economical process, prices in range $0.35–0.53/m3 rates up $60/1000 kg needed while keeping below $2/kg.

参考文章(78)
Dae Han Kim, Jae Layng Park, Eun Ji Park, Young Dok Kim, Sunghyun Uhm, Dopant Effect of Barium Zirconate-Based Perovskite-Type Catalysts for the Intermediate-Temperature Reverse Water Gas Shift Reaction ACS Catalysis. ,vol. 4, pp. 3117- 3122 ,(2014) , 10.1021/CS500476E
J. Díez-Ramírez, F. Dorado, A. Martínez-Valiente, J.M. García-Vargas, P. Sánchez, Kinetic, energetic and exergetic approach to the methane tri-reforming process International Journal of Hydrogen Energy. ,vol. 41, pp. 19339- 19348 ,(2016) , 10.1016/J.IJHYDENE.2016.04.229
Qinghe Zheng, Robert Farrauto, Anh Chau Nguyen, Adsorption and Methanation of Flue Gas CO2 with Dual Functional Catalytic Materials: A Parametric Study Industrial & Engineering Chemistry Research. ,vol. 55, pp. 6768- 6776 ,(2016) , 10.1021/ACS.IECR.6B01275
Giulia Bozzano, Flavio Manenti, Efficient methanol synthesis: Perspectives, technologies and optimization strategies Progress in Energy and Combustion Science. ,vol. 56, pp. 71- 105 ,(2016) , 10.1016/J.PECS.2016.06.001
Marcus Wenzel, Liisa Rihko-Struckmann, Kai Sundmacher, Thermodynamic analysis and optimization of RWGS processes for solar syngas production from CO2 AIChE Journal. ,vol. 63, pp. 15- 22 ,(2017) , 10.1002/AIC.15445
Pavlos Nikolaidis, Andreas Poullikkas, A comparative overview of hydrogen production processes Renewable & Sustainable Energy Reviews. ,vol. 67, pp. 597- 611 ,(2017) , 10.1016/J.RSER.2016.09.044
Chundong Zhang, Ki-Won Jun, Ruxing Gao, Geunjae Kwak, Hae-Gu Park, Carbon dioxide utilization in a gas-to-methanol process combined with CO2/Steam-mixed reforming: Techno-economic analysis Fuel. ,vol. 190, pp. 303- 311 ,(2017) , 10.1016/J.FUEL.2016.11.008
Bican Dai, Guilin Zhou, Shaobing Ge, Hongmei Xie, Zhaojie Jiao, Guizhi Zhang, Kun Xiong, CO2 reverse water-gas shift reaction on mesoporous M-CeO2 catalysts Canadian Journal of Chemical Engineering. ,vol. 95, pp. 634- 642 ,(2017) , 10.1002/CJCE.22730
Marcus Wenzel, N.V.R. Aditya Dharanipragada, Vladimir V. Galvita, Hilde Poelman, Guy B. Marin, Liisa Rihko-Struckmann, Kai Sundmacher, CO production from CO2 via reverse water–gas shift reaction performed in a chemical looping mode: Kinetics on modified iron oxide Journal of CO 2 Utilization. ,vol. 17, pp. 60- 68 ,(2017) , 10.1016/J.JCOU.2016.10.015