Electrochemical reactions of some metal species in amide-type ionic liquids

摘要: Some characteristic properties of the ionic liquids composed bis(trifluoromethylsulfonyl)amide (TFSA−) have been discussed based on our experimental results electrochemical reactions some metal species. Electrode potentials species are affected by coordination environment cations. The coordinated TFSA− is suitable for electrodeposition since reduction potential most positive in TFSA−-based liquids. Diffusion a charged determined not only size but also charge density Outer-sphere electron transfer sluggish due to slow dynamics ions On other hand, electrode involving surface processes considered electric double layer structure dependent potential. suggested act as dielectric media.