作者: David D. Schnaars , Richard E. Wilson
DOI: 10.1021/IC501553M
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摘要: We present the structural and spectroscopic characterization of six uranyl tetrachloride compounds along with a quantified analysis showing influence both crystallographic phase lattice solvent upon vibrational properties moiety. From symmetric asymmetric stretching frequencies we use valence bond potential model to calculate interaction force constants moiety in each compound. Quantifying these second-sphere influences provides insight into properties, indirectly electronic structure, ion its ground state. These data provide better guide for assessing validity future comparisons respect strength, length, among series actinyl where non-actinide variables may be at play.