Correlation Function Approach to Radiationless Transitions
作者： Sighart Fischer
DOI: 10.1063/1.1674470
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摘要: The rate constant for radiationless transitions is expressed in terms of a correlation function similar to the Kubo formulas transport coefficients. A strong coupling theory interaction electron with molecular vibrations adopted analyze time dependent function. For large system, rapid convergence this found due interference effects. This fact taken into account by applying saddle point method integration. results directly show dependence upon energy difference between relevant electronic states as well displacement and distortions adiabatic potentials.
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