The statistical mechanics of inhomogeneous hard rod mixtures

摘要: The exact statistical mechanical solution to the problem of an equilibrium inhomogeneous classical one‐dimensional mixture hard rods is presented. From solution, thermodynamic properties, density profiles, and correlation functions rod fluids confined small regions (micropores) can be calculated. theory applied investigate microstructure, pore pressures, adsorption selectivity micropores in with binary mixtures. A prescription suggested for generalizing results higher dimensions.