Improved photoactivities for CO2 conversion and phenol degradation of α-Fe2O3 nanoparticles by co-coupling nano-sized BiPO4 and CuO to modulate electrons

作者: Shuangying Chen , Zhiyuan Mu , Rui Yan , Xuliang Zhang , Iltaf Khan

DOI: 10.1016/J.JALLCOM.2019.06.032

关键词:

摘要: Abstract It's highly desired to design and fabricate effective α-Fe2O3-based photocatalysts by increasing the surface area, promoting charge separation providing catalytic function. Herein, specific area-enlarged α-Fe2O3 (SE-FO) nanoparticles have been successfully synthesized a functional molecule-modulated phase-separated hydrothermal method, with high photocatalytic activities for CO2 conversion phenol degradation. The of SE-FO could be greatly improved coupling nano-sized BiPO4 via an in-situ introduction method. This is attributed coupled as high-energy platform accept photogenerated electrons from so enhance mainly means photovoltage spectra fluorescence spectra-related amount produced •OH species. Moreover, are further introducing proper nanocrystalline CuO simple impregnation process. It confirmed based on temperature-programmed desorption electrochemical reduction measurements that photoactivity introduced co-catalyst electron-induced reactions. Remarkably, optimized nanocomposite exhibits about 3-time improvement compared pristine α-Fe2O3. work would provide feasible route high-activity

参考文章(41)
Jing Qian, Zhenting Yang, Chengquan Wang, Kan Wang, Qian Liu, Ding Jiang, Yuting Yan, Kun Wang, One-pot synthesis of BiPO4 functionalized reduced graphene oxide with enhanced photoelectrochemical performance for selective and sensitive detection of chlorpyrifos Journal of Materials Chemistry A. ,vol. 3, pp. 13671- 13678 ,(2015) , 10.1039/C5TA02629F
Yunxin Liu, Jianxin Shi, Qing Peng, Yadong Li, CuO Quantum‐Dot‐Sensitized Mesoporous ZnO for Visible‐Light Photocatalysis Chemistry: A European Journal. ,vol. 19, pp. 4319- 4326 ,(2013) , 10.1002/CHEM.201203316
Guido Busca, Silvia Berardinelli, Carlo Resini, Laura Arrighi, Technologies for the removal of phenol from fluid streams: A short review of recent developments Journal of Hazardous Materials. ,vol. 160, pp. 265- 288 ,(2008) , 10.1016/J.JHAZMAT.2008.03.045
Peng Luan, Mingzheng Xie, Dening Liu, Xuedong Fu, Liqiang Jing, Effective charge separation in the rutile TiO2 nanorod-coupled α-Fe2O3 with exceptionally high visible activities Scientific Reports. ,vol. 4, pp. 6180- 6180 ,(2015) , 10.1038/SREP06180
Ge Yin, Masami Nishikawa, Yoshio Nosaka, Nagarajan Srinivasan, Daiki Atarashi, Etsuo Sakai, Masahiro Miyauchi, Photocatalytic Carbon Dioxide Reduction by Copper Oxide Nanocluster-Grafted Niobate Nanosheets ACS Nano. ,vol. 9, pp. 2111- 2119 ,(2015) , 10.1021/NN507429E
Mingzheng Xie, Xuedong Fu, Liqiang Jing, Peng Luan, Yujie Feng, Honggang Fu, Long‐Lived, Visible‐Light‐Excited Charge Carriers of TiO2/BiVO4 Nanocomposites and their Unexpected Photoactivity for Water Splitting Advanced Energy Materials. ,vol. 4, pp. 1300995- ,(2014) , 10.1002/AENM.201300995
Wan‐Jing Yu, Lili Zhang, Peng‐Xiang Hou, Feng Li, Chang Liu, Hui‐Ming Cheng, None, High Reversible Lithium Storage Capacity and Structural Changes of Fe2O3 Nanoparticles Confined inside Carbon Nanotubes Advanced Energy Materials. ,vol. 6, pp. 1501755- ,(2016) , 10.1002/AENM.201501755
Wanting Sun, Qingqiang Meng, Liqiang Jing, Dening Liu, Yue Cao, Facile Synthesis of Surface-Modified Nanosized α-Fe2O3 as Efficient Visible Photocatalysts and Mechanism Insight Journal of Physical Chemistry C. ,vol. 117, pp. 1358- 1365 ,(2013) , 10.1021/JP309599D
Dandan Zhou, Zhengxue Xu, Shanshan Dong, Mingxin Huo, Shuangshi Dong, Xiadi Tian, Bin Cui, Houfeng Xiong, Tingting Li, Dongmei Ma, Intimate Coupling of Photocatalysis and Biodegradation for Degrading Phenol Using Different Light Types: Visible Light vs UV Light. Environmental Science & Technology. ,vol. 49, pp. 7776- 7783 ,(2015) , 10.1021/ACS.EST.5B00989