Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes.
作者： Silvio Aime , Alessandro Barge , Andrei S. Batsanov , Mauro Botta , Daniela Delli Castelli
DOI: 10.1039/B202862J
关键词:
摘要: The rate of axial water exchange in well-defined series lanthanide complexes depends on the extent second sphere hydration which is determined by complex hydrophobicity and nature ion its counter-ion.
rsc.org
sci-hub.se 参考文章(7)
Shanrong Zhang, Patrick Winter, Kuangcong Wu, A. Dean Sherry, A Novel Europium(III)-Based MRI Contrast Agent Journal of the American Chemical Society. ,vol. 123, pp. 1517- 1518 ,(2001) , 10.1021/JA005820Q
Silvio Aime, Alessandro Barge, Mauro Botta, Alvaro S. De Sousa, David Parker, Direct NMR Spectroscopic Observation of a Lanthanide-Coordinated Water Molecule whose Exchange Rate Is Dependent on the Conformation of the Complexes Angewandte Chemie International Edition. ,vol. 37, pp. 2673- 2675 ,(1998) , 10.1002/(SICI)1521-3773(19981016)37:19<2673::AID-ANIE2673>3.0.CO;2-#
Silvio Aime, Alessandro Barge, James I. Bruce, Mauro Botta, Judith A. K. Howard, Janet M. Moloney, David Parker, Alvaro S. de Sousa, Mark Woods, NMR, Relaxometric, and Structural Studies of the Hydration and Exchange Dynamics of Cationic Lanthanide Complexes of Macrocyclic Tetraamide Ligands Journal of the American Chemical Society. ,vol. 121, pp. 5762- 5771 ,(1999) , 10.1021/JA990225D
Rachel S. Dickins, Judith A. K. Howard, Christian W. Lehmann, Janet Moloney, David Parker, Robert D. Peacock, Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10-Tetraazacyclododecane Angewandte Chemie International Edition in English. ,vol. 36, pp. 521- 523 ,(1997) , 10.1002/ANIE.199705211
Frank A. Dunand, Silvio Aime, André E. Merbach, First 17O NMR Observation of Coordinated Water on Both Isomers of [Eu(DOTAM)(H2O)]3+: A Direct Access to Water Exchange and its Role in the Isomerization Journal of the American Chemical Society. ,vol. 122, pp. 1506- 1512 ,(2000) , 10.1021/JA993204S
Shanrong Zhang, Kuangcong Wu, Michael C. Biewer, A. Dean Sherry, 1H and 17O NMR Detection of a Lanthanide-Bound Water Molecule at Ambient Temperatures in Pure Water as Solvent Inorganic Chemistry. ,vol. 40, pp. 4284- 4290 ,(2001) , 10.1021/IC0003877
Shahid Amin, Janet R. Morrow, Charles H. Lake, Melvyn Rowen Churchill, Lanthanide(III) Tetraamide Macrocyclic Complexes as Synthetic Ribonucleases: Structure and Catalytic Properties of [La(tcmc)(CF3SO3)(EtOH)](CF3SO3)2 Angewandte Chemie. ,vol. 33, pp. 773- 775 ,(1994) , 10.1002/ANIE.199407731