Reactions and properties of some trimethyleneplatinum(IV) complexes : I. Thermal decomposition studies

作者: Peter W. Hall , Richard J. Puddephatt , Kenneth R. Seddon , Charles F.H. Tipper

DOI: 10.1016/S0022-328X(00)88212-1

关键词:

摘要: Abstract The thermal decomposition of the complexes PtX2(C3H6), PtX2(C3H6)L2 and PtX2(C3H6)(LL) [where X = Cl, Br; L pyridine, 4-methylpyridine; LL 2,2′-bipyridyl, ethylenediamine] has been studied by differential scanning calorimetry thermogravimetric analysis. first estimated PtC bond strength for platinum—trimethylene is reported.

参考文章(13)
B. Voigt, G. Adam, Photochemische cycloaddition von äthylen an 3-dehydro-gibberellin A3☆ Tetrahedron Letters. ,vol. 16, pp. 1937- 1938 ,(1975) , 10.1016/S0040-4039(00)72327-6
P.W. Hall, R.J. Puddephatt, C.F.H. Tipper, 1H,13 and 195Pt NMR studies of some platinumcyclopropane compounds Journal of Organometallic Chemistry. ,vol. 71, pp. 145- 151 ,(1974) , 10.1016/S0022-328X(00)93149-8
David Basset Brown, The reaction of cyclopropane with zeise's salt Journal of Organometallic Chemistry. ,vol. 24, pp. 787- 790 ,(1970) , 10.1016/S0022-328X(00)84512-X
R.D. Gillard, M Keeton, R. Mason, M.F. Pilbrow, D.R. Russell, Cyclopropane complexes of platinum: some sunthetic studies and the reactivity and crystal structure of 1,6-dichloro-2,3-trimethylene-4,5-bis(pyridine)platinum(IV) Journal of Organometallic Chemistry. ,vol. 33, pp. 247- 258 ,(1971) , 10.1016/S0022-328X(00)88414-4
T.G. Appleton, H.C. Clark, L.E. Manzer, The trans-influence: its measurement and significance Coordination Chemistry Reviews. ,vol. 10, pp. 335- 422 ,(1973) , 10.1016/S0010-8545(00)80238-6
D. M. Adams, J. Chatt, R. G. Guy, N. Sheppard, 149. The structure of “cyclopropane platinous chloride” J. Chem. Soc.. ,vol. 0, pp. 738- 742 ,(1961) , 10.1039/JR9610000738
S. E. Binns, R. H. Cragg, R. D. Gillard, B. T. Heaton, M. F. Pilbrow, Nature of Tipper's compound, dichlorotrimethyleneplatinum(IV) tetramer Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 1227- 1231 ,(1969) , 10.1039/J19690001227
W.J. Irwin, F.J. McQuillin, The chemistry of cyclopropane PtCl2 complexes Tetrahedron Letters. ,vol. 9, pp. 1937- 1940 ,(1968) , 10.1016/S0040-4039(01)99060-4