Ultrafast optical nonlinearity of titanylphthalocyanine films

作者: Guohong Ma , Lijun Guo , Jun Mi , Ye Liu , Shixiong Qian

DOI: 10.1016/S0040-6090(02)00246-8

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摘要: Abstract The optical properties of titanylphthalocyanine (TiOPc) thin film fabricated by physical jet deposition technique were investigated using absorption, femtosecond (fs) Kerr effect (OKE) and fs pump–probe techniques. third-order nonlinear susceptibility TiOPc was measured to be 3×10 −10 esu. OKE response films shows a decay process with subpicosecond time constant, demonstrating that the excited state molecule has little contribution photo-induced birefringence. From experiment, complicated behavior three components observed, which originates from exciton–exciton annihilation process, enhanced intersystem crossing relaxation triplet state.

参考文章(23)
Akira Terasaki, Masahiro Hosoda, Tatsuo Wada, Hirokazu Tada, Atsushi Koma, Akira Yamada, Hiroyuki Sasabe, Anthony F. Garito, Takayoshi Kobayashi, Femtosecond spectroscopy of vanadyl phthalocyanines in various molecular arrangements The Journal of Physical Chemistry. ,vol. 96, pp. 10534- 10542 ,(1992) , 10.1021/J100204A075
Akira Yamashita, Tohru Maruno, Takayoshi Hayashi, Phase-Selective Formation of Titanylphthalocyanine Thin Films by Organic Molecular Beam Deposition The Journal of Physical Chemistry. ,vol. 98, pp. 12695- 12701 ,(1994) , 10.1021/J100099A037
M. A. Díaz‐García, J. M. Cabrera, F. Agulló‐López, J. A. Duro, G. de la Torre, T. Torres, F. Fernández‐Lázaro, P. Delhaes, C. Mingotaud, Third‐order nonlinear optical susceptibilities of the Langmuir–Blodgett films of octa‐substituted metallophthalocyanines Applied Physics Letters. ,vol. 69, pp. 293- 295 ,(1996) , 10.1063/1.118037
J. Mizuguchi, G. Rihs, H. R. Karfunkel, Solid-State Spectra of Titanylphthalocyanine As Viewed from Molecular Distortion The Journal of Physical Chemistry. ,vol. 99, pp. 16217- 16227 ,(1995) , 10.1021/J100044A004
Ping Yuan, Zongju Xia, Y.H. Zou, Ling Quiu, Jifeng Shen, Yuquan Shen, Huijun Xu, Ultrafast optical Kerr effect of phthalocyanine Chemical Physics Letters. ,vol. 224, pp. 101- 105 ,(1994) , 10.1016/0009-2614(94)00510-9
S. Hughes, G. Spruce, J. M. Burzler, R. Rangel-Rojo, B. S. Wherrett, Theoretical analysis of the picosecond, induced absorption exhibited by chloroaluminum phthalocyanine Journal of The Optical Society of America B-optical Physics. ,vol. 14, pp. 400- 404 ,(1997) , 10.1364/JOSAB.14.000400
Jan Ern, Alexander Bock, Lionel Oddos-Marcel, Heiko Rengel, Gerhard Wegner, H. Peter Trommsdorff, Carola Kryschi, Femtosecond Study of Exciton Transport Dynamics in (Phthalocyaninato)polysiloxane Journal of Physical Chemistry A. ,vol. 103, pp. 2446- 2450 ,(1999) , 10.1021/JP984064W
Tai-Huei Wei, Tzer-Hsiang Huang, Mu-Shih Lin, Signs of nonlinear refraction in chloroaluminum phthalocyanine solution Applied Physics Letters. ,vol. 72, pp. 2505- 2507 ,(1998) , 10.1063/1.121401
Shoichi Yamaguchi, Yutaka Sasaki, Primary carrier-generation process in Y-form and phase I titanyl phthalocyanines Chemical Physics Letters. ,vol. 323, pp. 35- 42 ,(2000) , 10.1016/S0009-2614(00)00475-9