Functionalization s. β-elimination in alkane activation: a key role for 16-electron ML5 intermediates

作者: Odile Eisenstein , Robert H. Crabtree

DOI: 10.1039/B101336J

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摘要: The structural preferences in the intermediate ML5 d6 alkyls are proposed to help determine reactivity difference between Shilov systems, which convert R–H R–X ia reductive elimination, and alkane dehydrogenation catalysis, where is converted alkene, ia β-elimination of an R–M intermediate.

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