Synthetic Studies on Aphidicolane and Stemodane Diterpenes. III.An Alternative Stereoselective Access to Aphidicolane-Type B/C/D-Ring System

作者: Tetsuaki TANAKA , Kaszuo MURAKAMI , Osamu OKUDA , Takeshi KURODA , Tetsuya INOUE

DOI: 10.1248/CPB.42.1756

关键词:

摘要: Compound 2, corresponding to the B/C/D-ring for aphidicolane-type diterpenes, was synthesized stereoselectively from a perhydroindane derivative (3) which obtained by rhodium-alumina catalyzed hydrogenation of an indane ester (4) as key step.

参考文章(1)
Richard C. Larock, Reagents for Organic Synthesis ,(1967)