Effects of Ce3+ Codoping and Annealing on Phase Transformation and Luminescence of Eu3+-Doped YPO4 Nanorods: D2O Solvent Effect

作者: M Niraj Luwang , RS Ningthoujam , SK Srivastava , RK Vatsa , None

DOI: 10.1021/JA909578S

关键词:

摘要: Ce3+- and Eu3+-doped YPO4 nanorods have been prepared at relatively low temperature (120 °C). A detailed investigation of the role Ce3+ concentration up to 10 atom % on luminescence intensity Eu3+ in has carried out. Phase transformation from a tetragonal hexagonal structure occurs with increasing concentrations, water molecules are also associated during phase transformation. Thermal study shows that can be retained 800 °C structure. Interestingly, returns annealing above 900 °C. As-prepared 500 heated samples show uniform sized nanorods, whereas sample distorted which pores present. Initially, decreases sharply even for 2 %. This is related enhanced nonradiative rate as compared radiative rate, since multiphonon relaxation surrounding wat...

参考文章(33)
Zhi Min Fang, Qi Hong, Zhao Hui Zhou, Shen Jun Dai, Wei Zheng Weng, Hui Lin Wan, Oxidative dehydrogenation of propane over a series of low-temperature rare earth orthovanadate catalysts prepared by the nitrate method Catalysis Letters. ,vol. 61, pp. 39- 44 ,(1999) , 10.1023/A:1019096116289
RS Ningthoujam, V Sudarsan, SV Godbole, L Kienle, SK Kulshreshtha, AK Tyagi, None, SnO2: Eu3+ nanoparticles dispersed in TiO2 matrix: Improved energy transfer between semiconductor host and Eu3+ ions for the low temperature synthesized samples Applied Physics Letters. ,vol. 90, pp. 173113- ,(2007) , 10.1063/1.2731433
Weihua Di, Xiaojun Wang, Baojiu Chen, Shaozhe Lu, Xinguang Ren, Experimental demonstration of the relationship between the OH− content and photoluminescence in Tb-doped YPO4∙2H2O Applied Physics Letters. ,vol. 88, pp. 011907- ,(2006) , 10.1063/1.2158703
RS Ningthoujam, R Shukla, RK Vatsa, V Duppel, L Kienle, AK Tyagi, None, Gd2O3:Eu3+ particles prepared by glycine-nitrate combustion: Phase, concentration, annealing, and luminescence studies Journal of Applied Physics. ,vol. 105, pp. 084304- ,(2009) , 10.1063/1.3098253
Dosi Dosev, Mikaela Nichkova, Maozi Liu, Bing Guo, Gang-yu Liu, Bruce D. Hammock, Ian M. Kennedy, Application of luminescent Eu: Gd2O3 nanoparticles to the visualization of protein micropatterns Journal of Biomedical Optics. ,vol. 10, pp. 064006- 064006 ,(2005) , 10.1117/1.2136347
Syouhei Nishihama, Takayuki Hirai, Isao Komasawa, The preparation of rare earth phosphate fine particles in an emulsion liquid membrane system Journal of Materials Chemistry. ,vol. 12, pp. 1053- 1057 ,(2002) , 10.1039/B105743J
Tetsuya Taima, Masayuki Chikamatsu, Raghu Nath Bera, Yuji Yoshida, Kazuhiro Saito, Kiyoshi Yase, Insertion of thin interlayers under the negative electrode of C60 Schottky-type photovoltaic cells Journal of Physical Chemistry B. ,vol. 108, pp. 1- 3 ,(2004) , 10.1021/JP037237C
J.M. Nedelec, C. Mansuy, R. Mahiou, Sol–gel derived YPO4 and LuPO4 phosphors, a spectroscopic study Journal of Molecular Structure. ,vol. 651, pp. 165- 170 ,(2003) , 10.1016/S0022-2860(03)00104-2
L Robindro Singh, RS Ningthoujam, V Sudarsan, Iti Srivastava, S Dorendrajit Singh, GK Dey, SK Kulshreshtha, None, Luminescence study on Eu(3+) doped Y(2)O(3) nanoparticles: particle size, concentration and core-shell formation effects. Nanotechnology. ,vol. 19, pp. 055201- ,(2008) , 10.1088/0957-4484/19/05/055201
Hongwei Song, Lixin Yu, Shaozhe Lu, Tie Wang, Zhongxin Liu, Linmei Yang, Remarkable differences in photoluminescent properties between LaPO4:Eu one-dimensional nanowires and zero-dimensional nanoparticles Applied Physics Letters. ,vol. 85, pp. 470- 472 ,(2004) , 10.1063/1.1773616