Picoseconds time resolved photoinduced absorption by infrared active vibrations as a probe for charge photogeneration in MEH-PPV/C60 composites

作者: U. Mizrahi , I. Shtrichman , D. Gershoni , E. Ehrenfreund , Z.V. Vardeny

DOI: 10.1016/S0379-6779(98)00316-6

关键词:

摘要: Abstract We have applied a visible pump mid-infrared probe picosecond time resolved technique, in order to study the photogeneration of charges MEH-PPV/C 60 composites. The photoinduced infrared active vibrations on polymer chains been used as direct measure for photogenerated charges. found that, within our resolution ⋍60 ps, polarons are MEH-PPV with quantum yield 5%.

参考文章(17)
Alan J Heeger, Steven Kivelson, John Robert Schrieffer, W-P Su, None, Solitons in conducting polymers Reviews of Modern Physics. ,vol. 60, pp. 781- 850 ,(1988) , 10.1103/REVMODPHYS.60.781
Shigenori Morita, Anvar A Zakhidov, Katsumi Yoshino, Doping effect of buckminsterfullerene in conducting polymer: Change of absorption spectrum and quenching of luminescene Solid State Communications. ,vol. 82, pp. 249- 252 ,(1992) , 10.1016/0038-1098(92)90636-N
N. S. Sariciftci, L. Smilowitz, A. J. Heeger, F. Wudl, Photoinduced electron transfer from a conducting polymer to buckminsterfullerene. Science. ,vol. 258, pp. 1474- 1476 ,(1992) , 10.1126/SCIENCE.258.5087.1474
R. Duet, D. Gershoni, E. Ehrenfreund, Picosecond dynamics of quantum structure carriers measured by time resolved photoinduced intersubband absorption Superlattices and Microstructures. ,vol. 17, pp. 5- 9 ,(1995) , 10.1006/SPMI.1995.1002
B. Kraabel, D. McBranch, N. S. Sariciftci, D. Moses, A. J. Heeger, Ultrafast spectroscopic studies of photoinduced electron transfer from semiconducting polymers to C60. Physical Review B. ,vol. 50, pp. 18543- 18552 ,(1994) , 10.1103/PHYSREVB.50.18543
M. Olszakier, E. Ehrenfreund, E. Cohen, J. Bajaj, G. J. Sullivan, Photoinduced intersubband absorption in undoped multi-quantum-well structures. Physical Review Letters. ,vol. 62, pp. 2997- 3000 ,(1989) , 10.1103/PHYSREVLETT.62.2997
Kwanghee Lee, Rene A. J. Janssen, N. S. Sariciftci, A. J. Heeger, Direct evidence of photoinduced electron transfer in conducting-polymer-C60 composites by infrared photoexcitation spectroscopy. Physical Review B. ,vol. 49, pp. 5781- 5784 ,(1994) , 10.1103/PHYSREVB.49.5781
X. Wei, Z. V. Vardeny, N. S. Sariciftci, A. J. Heeger, Absorption-detected magnetic-resonance studies of photoexcitations in conjugated-polymer/C60 composites Physical Review B. ,vol. 53, pp. 2187- 2190 ,(1996) , 10.1103/PHYSREVB.53.2187
R. Duer, I. Shtrichman, D. Gershoni, E. Ehrenfreund, Momentum Redistribution Times of Resonantly Photogenerated 2D Excitons Physical Review Letters. ,vol. 78, pp. 3919- 3922 ,(1997) , 10.1103/PHYSREVLETT.78.3919
M.G. Harrison, K.E. Ziemelis, R.H. Friend, P.L. Burn, A.B. Holmes, Optical spectroscopy of field-induced charge in poly(2.5-dimethoxy-p-phenylene vinylene) metal-insulator-semiconductor structures Synthetic Metals. ,vol. 55, pp. 218- 223 ,(1993) , 10.1016/0379-6779(93)90936-Q