Photostabilising effect of bis(hindered piperidine) compounds: Part II—In singlet-oxygen degradation of cis-1,4-poly(butadiene)

作者: Yung Yuan Yang , Julia Lucki , Jan F. Rabek , Bengt Rånby

DOI: 10.1016/0144-2880(83)90072-6

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摘要: Abstract Three commercially available bis(hindered piperidines)—Tinuvin 144 (Bis (1,2,2,6,6-pentamethyl-4-piperidinyl)-2-n-butyl-2-(3,5-di-tert-butyl-4-hydroxy-benzyl)malonate); Tinuvin 292 (Bis(1,2,2,6,6-pentamethyl-4-piperidinyl)sebacate) and 770 (Bis(2,2,6,6-tetramethyl-4-piperidinyl)sebacate)—have been found to be effective deactivators of singlet oxygen generated in the gas phase by microwaves solution a dye photosensitised reaction. These three stabilisers effectively protec cis-1,4-polybutadiene against oxidation.

参考文章(28)
D. Lala, J.F. Rabek, B. Ranby, The effect of 1,3-diphenylisobenzofuran on the photo-oxidative degradation of cis-1,4-polybutadiene European Polymer Journal. ,vol. 16, pp. 735- 744 ,(1980) , 10.1016/0014-3057(80)90042-7
Daniel Bellus, Hanns Lind, John F. Wyatt, Quenching of singlet (1? g ) oxygen by 2,2,6,6-tetramethylpiperidine derivatives Journal of the Chemical Society, Chemical Communications. pp. 1199- 1200 ,(1972) , 10.1039/C39720001199
David R. Kearns, Ahsan U. Khan, Sensitized photooxygenation reactions and the role of singlet oxygen. Photochemistry and Photobiology. ,vol. 10, pp. 193- 210 ,(1969) , 10.1111/J.1751-1097.1969.TB05679.X
P.B. Merkel, D.R. Kearns, Direct measurement of the lifetime of 1Δ oxygen in solution Chemical Physics Letters. ,vol. 12, pp. 120- 122 ,(1971) , 10.1016/0009-2614(71)80630-9
A. Rigo, E. Argese, R. Stevanato, E.F. Orsega, P. Viglino, A new method of detecting O2− production Inorganica Chimica Acta. ,vol. 24, pp. 71- 73 ,(1977) , 10.1016/S0020-1693(00)93831-3
Y. LION, M. DELMELLE, A. VAN DE VORST, New method of detecting singlet oxygen production Nature. ,vol. 263, pp. 442- 443 ,(1976) , 10.1038/263442A0
Robert H. Young, David. Brewer, Richard A. Keller, Determination of rate constants of reaction and lifetimes of singlet oxygen in solution by a flash photolysis technique Journal of the American Chemical Society. ,vol. 95, pp. 375- 379 ,(1973) , 10.1021/JA00783A012
David R. Kearns, Physical and chemical properties of singlet molecular oxygen Chemical Reviews. ,vol. 71, pp. 395- 427 ,(1971) , 10.1021/CR60272A004