Thermal behavior of some long-chain quaternary ammonium salts

作者: G. Margomenou-Leonidopoulou , A. Malliaris , C.M. Paleos

DOI: 10.1016/0040-6031(85)85551-9

关键词:

摘要: Abstract In the present work synthesis and thermal behavior of some long - chain quaternary ammonium salts functionalized in polar head, formula C12H25 N + (CH3)2 RBr−, are reported. It has been found that these form, through a solid-solid transition, peculiar solid phase liquid-like character they also exhibit improved stability compared to non-functionalized n-alkyltrimethylammonium bromides. Furthermore thermodynamic parameters compounds dependent complicated way on nature functional group.

参考文章(9)
Kazutoshi Iwamoto, Yukio Ohnuki, Kiyoshi Sawada, Manabu Senō, Solid-Solid Phase Transitions of Long-Chain n-Alkyltrimethylammonium Halides Molecular Crystals and Liquid Crystals. ,vol. 73, pp. 95- 103 ,(1981) , 10.1080/00268948108076264
Angelos Malliaris, C.M Paleos, Micellar properties of quaternary ammonium surfactants bearing OH and COOH functional groups on their ionic heads Journal of Colloid and Interface Science. ,vol. 101, pp. 364- 368 ,(1984) , 10.1016/0021-9797(84)90046-8
M. Vacatello, V. Busico, On the Liquid Crystalline Behaviour of Bis(n-Penta-Decylammonium)Tetrabromozincate Molecular Crystals and Liquid Crystals. ,vol. 64, pp. 127- 132 ,(1981) , 10.1080/01406568108072517
A. Malliaius, C. Christias, G. Margomenou-lmonidopoulou, C. M. Paleos, Single Chain Quaternary Ammonium Salts Exhibiting Thermotropic Mesomorehism and Organization in Water Molecular Crystals and Liquid Crystals. ,vol. 82, pp. 161- 166 ,(1982) , 10.1080/01406568208070137
Vincenzo Busico, Domenico Castaldo, Michele Vacatello, Thermal Behavior and Liquid Crystalline Phases of a Series of Bis (n-Alkylammonium) Tetrabromozincates Molecular Crystals and Liquid Crystals. ,vol. 78, pp. 221- 226 ,(1981) , 10.1080/00268948108082159
Vincenzo Busico, Paolo Corradini, Michele Vacatello, Thermal behavior and observation of a smectic phase in n-pentadecylammonium chloride The Journal of Physical Chemistry. ,vol. 86, pp. 1033- 1034 ,(1982) , 10.1021/J100395A040
Vincenzo Busico, Piero Cernicchiaro, Paolo Corradini, Michele Vacatello, Polymorphism in anhydrous amphiphilic systems. Long-chain primary n-alkylammonium chlorides The Journal of Physical Chemistry. ,vol. 14, pp. 1631- 1635 ,(1983) , 10.1021/J100232A035
A. Cingolani, G. Spinolo, M. Sanesi, P. Franzosini, On the Thermal Behaviour of the n.C 13 - n.C 20 Potassium Alkanoates Zeitschrift Fur Naturforschung Section A-a Journal of Physical Sciences. ,vol. 35, pp. 757- ,(1980) , 10.1515/ZNA-1980-0715