Vapor−Liquid Equilibrium and Volumetric Measurements for Binary Mixtures of 1,4-Dioxane with Isomeric Chlorobutanes
作者： Antonio Reyes , Marta Haro , Ignacio Gascón , Héctor Artigas , Carlos Lafuente
DOI: 10.1021/JE020185K
关键词:
摘要: Volumetric and isobaric vapor−liquid equilibrium measurements are reported for 1,4-dioxane + 1-chlorobutane, 2-chlorobutane, 2-methyl-1-chloropropane, 2-chloro-2-methylpropane. From density measurements, excess volumes have been calculated correlated with a Redlich−Kister equation. The VLE data thermodynamically consistent were well Margules, Van Laar, Wilson, NRTL, UNIQUAC equations. results compared to the predictions by UNIFAC ASOG methods.
acs.org
sci-hub.se 参考文章(17)
Norman Silverman, Dimitrios Tassios, Prediction of multicomponent vapor-liquid equilibrium with the Wilson equation: effect of the minimization function and of the quality of binary data Industrial & Engineering Chemistry Process Design and Development. ,vol. 23, pp. 586- 589 ,(1984) , 10.1021/I200026A030
Lewis C. Yen, S. S. Woods, A generalized equation for computer calculation of liquid densities AIChE Journal. ,vol. 12, pp. 95- 99 ,(1966) , 10.1002/AIC.690120119
Pilar Brocos, Encina Calvo, Alfredo Amigo, Ramón Bravo, Mercedes Pintos, Alain H. Roux, Geneviève Roux-Desgranges, Heat capacities, excess enthalpies, and volumes of mixtures containing cyclic ethers. 2. Binary systems 1,3-dioxolane + n-alkanes Journal of Chemical & Engineering Data. ,vol. 43, pp. 1341- 1347 ,(1998) , 10.1021/JE9701947
Aage Fredenslund, Russell L. Jones, John M. Prausnitz, Group‐contribution estimation of activity coefficients in nonideal liquid mixtures Aiche Journal. ,vol. 21, pp. 1086- 1099 ,(1975) , 10.1002/AIC.690210607
Otto. Redlich, J. N. S. Kwong, On the Thermodynamics of Solutions. V. An Equation of State. Fugacities of Gaseous Solutions. Chemical Reviews. ,vol. 44, pp. 233- 244 ,(1949) , 10.1021/CR60137A013
H. Artigas, C. Lafuente, M.C. López, F.M. Royo, J.S. Urieta, Vapour-liquid equilibrium for the binary systems of 2-methyl-1-propanol with some halohydrocarbons at 40.0 and 101.3 kPa Fluid Phase Equilibria. ,vol. 134, pp. 163- 174 ,(1997) , 10.1016/S0378-3812(97)00060-5
H. Artigas, C. Lafuente, M. C. Lopez, F. M. Royo, J. S. Urieta, Isobaric Vapor-Liquid Equilibria for Binary Mixtures of 1-Chlorobutane with Isomeric Butanols at 40.0 and 101.3 kPa Journal of Chemical & Engineering Data. ,vol. 39, pp. 729- 732 ,(1994) , 10.1021/JE00016A021
Juergen Gmehling, Jiding Li, Martin Schiller, A modified UNIFAC model. 2. Present parameter matrix and results for different thermodynamic properties Industrial & Engineering Chemistry Research. ,vol. 32, pp. 178- 193 ,(1993) , 10.1021/IE00013A024
I. Gascón, M. Domínguez, P. Cea, M.C. López, F.M. Royo, Isobaric (vapour + liquid) equilibrium of (1,3-dioxolane, or 1,4-dioxane + 1-butanol, or 2-butanol) at 40.0 kPa and 101.3 kPa The Journal of Chemical Thermodynamics. ,vol. 33, pp. 1361- 1373 ,(2001) , 10.1006/JCHT.2001.0842
Hendrick C. Van Ness, Stanley M. Byer, Richard E. Gibbs, Vapor‐Liquid equilibrium: Part I. An appraisal of data reduction methods Aiche Journal. ,vol. 19, pp. 238- 244 ,(1973) , 10.1002/AIC.690190206