Effect of reducing calcination processing on structural and electrochemical properties of LiNi0.5Mn0.3Co0.2O2 cathode materials for lithium battery

作者: Sukum Eitssayeam , Jaruwan Kanthachan , Uraiwan Intatha , Orawan Khamman

DOI: 10.1016/J.MATPR.2021.03.691

关键词:

摘要: Abstract Lithium-ion batteries (LIBs) are capable of meeting the challenges associated with next-generation energy storage devices. Use NMC has grown at 400,000 tons per year in 2025. Because its performance surpassing that other cathode materials. Thus, this work, synthesis lithium nickel manganese cobalt oxide (LiNi0.5Mn0.3Co0.2O2; NMC) was doped carbon calcination process investigated. Excellent intercalation ions transfer between and anode noted. Differential Thermal Analysis (DTA) results showed crystalized 550 °C. Changes were confirmed by using both X-ray diffract meter (XRD) Scanning Electron Microscope (SEM). The study possibility materials which enhancement electrochemical investigated charge–discharge capacity 0.1C-rate carried out to reveal carbon's effect pristine NMC.

参考文章(12)
Lingjun Li, Qi Yao, Zhaoyong Chen, Liubin Song, Tian Xie, Huali Zhu, Junfei Duan, Kaili Zhang, Effects of lithium-active manganese trioxide coating on the structural and electrochemical characteristics of LiNi0.5Co0.2Mn0.3O2 as cathode materials for lithium ion battery Journal of Alloys and Compounds. ,vol. 650, pp. 684- 691 ,(2015) , 10.1016/J.JALLCOM.2015.08.041
P. Y. Liao, J. G. Duh, S. R. Sheen, Effect of Mn Content on the Microstructure and Electrochemical Performance of LiNi0.75 − xCo0.25MnxO2 Cathode Materials Journal of The Electrochemical Society. ,vol. 152, ,(2005) , 10.1149/1.1952687
Yang Zhao, Ying Huang, Qiufen Wang, Xiaoya Wang, Meng Zong, Carbon-doped Li2SnO3/graphene as an anode material for lithium-ion batteries Ceramics International. ,vol. 39, pp. 1741- 1747 ,(2013) , 10.1016/J.CERAMINT.2012.08.020
Xiaoyu Zhang, W.J. Jiang, A. Mauger, Qilu, F. Gendron, C.M. Julien, Minimization of the cation mixing in Li1+x(NMC)1−xO2 as cathode material Journal of Power Sources. ,vol. 195, pp. 1292- 1301 ,(2010) , 10.1016/J.JPOWSOUR.2009.09.029
EunJoo Yoo, Jedeok Kim, Eiji Hosono, Hao-shen Zhou, Tetsuichi Kudo, Itaru Honma, Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries. Nano Letters. ,vol. 8, pp. 2277- 2282 ,(2008) , 10.1021/NL800957B
Tarun Bhardwaj, Aleks Antic, Barbara Pavan, Veronica Barone, Bradley D. Fahlman, Enhanced Electrochemical Lithium Storage by Graphene Nanoribbons Journal of the American Chemical Society. ,vol. 132, pp. 12556- 12558 ,(2010) , 10.1021/JA106162F
A. K. Geim, Graphene: Status and Prospects Science. ,vol. 324, pp. 1530- 1534 ,(2009) , 10.1126/SCIENCE.1158877
Chaochao Fu, Guangshe Li, Dong Luo, Qi Li, Jianming Fan, Liping Li, Nickel-Rich Layered Microspheres Cathodes: Lithium/Nickel Disordering and Electrochemical Performance ACS Applied Materials & Interfaces. ,vol. 6, pp. 15822- 15831 ,(2014) , 10.1021/AM5030726
Yin Ding, Rui Wang, Lei Wang, Kailin Cheng, Zhikun Zhao, DaoBin Mu, Borong Wu, A Short Review on Layered LiNi0.8Co0.1Mn0.1O2 Positive Electrode Material for Lithium-ion Batteries Energy Procedia. ,vol. 105, pp. 2941- 2952 ,(2017) , 10.1016/J.EGYPRO.2017.03.672
Matthias Eilers-Rethwisch, Martin Winter, Falko Mark Schappacher, Synthesis, electrochemical investigation and structural analysis of doped Li[Ni0.6Mn0.2Co0.2-xMx]O2 (x = 0, 0.05; M = Al, Fe, Sn) cathode materials Journal of Power Sources. ,vol. 387, pp. 101- 107 ,(2018) , 10.1016/J.JPOWSOUR.2018.02.080