Uranium complexes supported by an aryloxide functionalised triazacyclononane macrocycle: synthesis and characterisation of a six-coordinate U(iii) species and insights into its reactivityElectronic supplementary information (ESI) available: synthetic and analytical results, including elemental analysis, for all new complexes, crystallographic information for 2 and 3, and computational details for 1, figures and tables. See http://www.rsc.org/suppdata/cc/b2/b208473b/

作者: Ingrid Castro-Rodriguez , Kristian Olsen , Peter Gantzel , Karsten Meyer

DOI: 10.1039/B208473B

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摘要: A reactive low-valent uranium(III) complex supported by an aryloxide functionalised triazacyclononane has been synthesised and provides a platform for enhanced uranium reactivity.

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