Immoblization of Thiol-Functionalized Nanosilica on the Surface of Poly(ether sulfone) Membranes for the Removal of Heavy-Metal Ions from Industrial Wastewater Samples
作者： Ahmad Rezvani-Boroujeni , Mehran Javanbakht , Mohammad Karimi , Cyrous Shahrjerdi , Behrouz Akbari-adergani
DOI: 10.1021/IE504106Y
关键词:
摘要: In this study, surface-immobilized thiol-functionalized nanosilica poly(ether sulfone) (PES) membranes were prepared to improve the membrane selectivity and wettability during filtration of heavy-metal solutions. The PES by phase inversion method create more open interconnected nanoporous structures. Nanosilica particles functionalized with 3-mercaptopropyltrimethoxysilane (MPTMS) initiate free thiol (−SH) groups on surface used as dispersed in ethanol. To increase adsorption nanoparticles surface, was treated Ar/O2 plasma before being immersed dispersion phase. cross-sectional morphology composition characterized scanning electron microscopy (SEM) energy-dispersive X-ray spectroscopy (EDS), respectively. Contact angle (CA) measurements confirmed that treatment improves membranes. Functionalized ...
acs.org
sci-hub.se 参考文章(61)
Michelle L. Steen, Alistair C. Jordan, Ellen R. Fisher, Hydrophilic modification of polymeric membranes by low temperature H2O plasma treatment Journal of Membrane Science. ,vol. 204, pp. 341- 357 ,(2002) , 10.1016/S0376-7388(02)00061-3
M. Najafi, Y. Yousefi, A.A. Rafati, SYNTHESIS, CHARACTERIZATION AND ADSORPTION STUDIES OF SEVERAL HEAVY METAL IONS ON AMINO-FUNCTIONALIZED SILICA NANO HOLLOW SPHERE AND SILICA GEL Separation and Purification Technology. ,vol. 85, pp. 193- 205 ,(2012) , 10.1016/J.SEPPUR.2011.10.011
Fei Zheng, Bin Hu, MPTS-silica coated capillary microextraction on line hyphenated with inductively coupled plasma atomic emission spectrometry for the determination of Cu, Hg and Pb in biological samples. Talanta. ,vol. 73, pp. 372- 379 ,(2007) , 10.1016/J.TALANTA.2007.03.060
Mehran Javanbakht, Hamid Khoshsafar, Mohammad Reza Ganjali, Parviz Norouzi, Alireza Badei, Abed Hasheminasab, Stripping Voltammetry of Cerium(IIl) with a Chemically Modified Carbon Paste Electrode Containing Functionalized Nanoporous Silica Gel Electroanalysis. ,vol. 20, pp. 203- 206 ,(2008) , 10.1002/ELAN.200704038
Norhan Nady, Maurice C.R. Franssen, Han Zuilhof, Mohamed S. Mohy Eldin, Remko Boom, Karin Schroën, Modification methods for poly(arylsulfone) membranes: A mini-review focusing on surface modification Desalination. ,vol. 275, pp. 1- 9 ,(2011) , 10.1016/J.DESAL.2011.03.010
Ming-Liang Luo, Jian-Qing Zhao, Wu Tang, Chun-Sheng Pu, Hydrophilic modification of poly(ether sulfone) ultrafiltration membrane surface by self-assembly of TiO2 nanoparticles Applied Surface Science. ,vol. 249, pp. 76- 84 ,(2005) , 10.1016/J.APSUSC.2004.11.054
Tae-Hyun Bae, Tae-Moon Tak, Effect of TiO2 nanoparticles on fouling mitigation of ultrafiltration membranes for activated sludge filtration Journal of Membrane Science. ,vol. 249, pp. 1- 8 ,(2005) , 10.1016/J.MEMSCI.2004.09.008
Yuqing Zhang, Zhenhua Jin, Xing Shan, Jaka Sunarso, Ping Cui, Preparation and characterization of phosphorylated Zr-doped hybrid silica/PSF composite membrane Journal of Hazardous Materials. ,vol. 186, pp. 390- 395 ,(2011) , 10.1016/J.JHAZMAT.2010.11.016
Y. Mansourpanah, S.S. Madaeni, A. Rahimpour, A. Farhadian, A.H. Taheri, Formation of appropriate sites on nanofiltration membrane surface for binding TiO2 photo-catalyst: Performance, characterization and fouling-resistant capability Journal of Membrane Science. ,vol. 330, pp. 297- 306 ,(2009) , 10.1016/J.MEMSCI.2009.01.001
T BAE, T TAK, Preparation of TiO2 self-assembled polymeric nanocomposite membranes and examination of their fouling mitigation effects in a membrane bioreactor system Journal of Membrane Science. ,vol. 266, pp. 1- 5 ,(2005) , 10.1016/J.MEMSCI.2005.08.014