Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane
作者： Guojiao Wu , Yifan Deng , Chaoqiang Wu , Xi Wang , Yan Zhang
关键词:
摘要: The transition-metal-free 2,2,2-trifluoroethylation and gem-difluorovinylation of arylboronic acids were developed. By employing different reaction conditions, these transformations provide both (2,2,2-trifluoroethyl)arenes gem-difluorovinylarenes from 2,2,2-trifluorodiazoethane. operation is simple scalable with good functional group tolerance.
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