The carbon isotopic distribution of Murchison amino acids

作者: Sandra Pizzarello , Yongsong Huang , Megan Fuller

DOI: 10.1016/J.GCA.2004.05.024

关键词:

摘要: Abstract The δ 13 C values of thirty-four individual amino acids and two pyridine carboxylic have been obtained fromthe Murchison meteorite. They were found to range from +4.9 +52.8‰, with statistically significant differences observed both within between acid subgroups. content α-amino declines increasing chain length, a trend similar the ones previously for alkanes. Also 2-methyl-2-amino be heavier in than corresponding 2-H homologues. The3-, 4-, 5-amino do not show comparable declining neither dicarboxylic acids. This variability can interpreted as indicate that synthetic histories soluble organics meteorites may diverse even groups compounds very functional group composition.

参考文章(34)
J W Keller, K B Baurick, G C Rutt, M V O'Malley, N L Sonafrank, R A Reynolds, L O Ebbesson, F F Vajdos, Pseudomonas cepacia 2,2-dialkylglycine decarboxylase. Sequence and expression in Escherichia coli of structural and repressor genes. Journal of Biological Chemistry. ,vol. 265, pp. 5531- 5539 ,(1990) , 10.1016/S0021-9258(19)39393-7
John R Cronin, Sandra Pizzarello, George U Yuen, Amino acids of the Murchison meteorite. II - Five carbon acyclic primary beta-, gamma-, and delta-amino alkanoic acids Geochimica et Cosmochimica Acta. ,vol. 49, pp. 2259- 2265 ,(1985) , 10.1016/0016-7037(85)90226-1
S. Pizzarello, J. R. Cronin, Alanine enantiomers in the Murchison meteorite Nature. ,vol. 394, pp. 236- 236 ,(1998) , 10.1038/28306
John R. Cronin, Sherwood Chang, Organic matter in meteorites: molecular and isotopic analyses of the Murchison meteorite. The Chemistry of Life's Origins. ,vol. 416, pp. 209- 258 ,(1993) , 10.1007/978-94-011-1936-8_9
Oliver Botta, Extraterrestrial Organic Compounds in Meteorites Surveys in Geophysics. ,vol. 23, pp. 411- 467 ,(2002) , 10.1023/A:1020139302770
EDWARD T. PELTZER, JEFFREY L. BADA, α-Hydroxycarboxylic acids in the Murchison meteorite Nature. ,vol. 272, pp. 443- 444 ,(1978) , 10.1038/272443A0
Jeffrey Bada, Oliver Bota, Pascale Ehrenfreund, Daniel P Glavin, Michael Meyer, George Cooper, Extraterrestrial amino acids in Orgueil and Ivuna: tracing the parent body of CI type carbonaceous chondrites. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 98, pp. 2138- 2141 ,(2001) , 10.1073/PNAS.051502898