Applications of Transition-Metal Catalysts to Textile and Wood-Pulp Bleaching

作者: Ronald Hage , Achim Lienke

DOI: 10.1002/ANIE.200500525

关键词:

摘要: From an economic perspective, textile and paper bleaching are amongst the most important oxidation processes. The removal of unwanted chromophores, be it stains on cloths or residual lignin in wood pulp, consumes more than 60% of the world production of hydrogen peroxide. However, existing technologies have their limitations. At ambient temperature, hydrogen peroxide gives little stain bleaching and is used inefficiently. Hence the high product dosages and washing temperatures required limit its application to predominantly …

参考文章(136)
DV Evtuguin, C Pascoal Neto, New polyoxometalate promoted method of oxygen delignification Holzforschung. ,vol. 51, pp. 338- 342 ,(1997)
DV Evtuguin, C Pascoal, JD Pedrosa de Jesus, Bleaching of kraft pulp by oxygen in the presence of polyoxometalates Journal of pulp and paper science. ,vol. 24, pp. 133- 139 ,(1998)
Hanne Hjorth T�nnesen, Jan Karlsen, Studies on curcumin and curcuminoids. VI. Kinetics of curcumin degradation in aqueous solution. European Food Research and Technology. ,vol. 180, pp. 402- 404 ,(1985) , 10.1007/BF01027775
R.M. Burger, J. Peisach, S.B. Horwitz, Activated bleomycin. A transient complex of drug, iron, and oxygen that degrades DNA. Journal of Biological Chemistry. ,vol. 256, pp. 11636- 11644 ,(1981) , 10.1016/S0021-9258(19)68452-8
M. H. Lim, J.-U. Rohde, A. Stubna, M. R. Bukowski, M. Costas, R. Y. N. Ho, E. Munck, W. Nam, L. Que, An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 100, pp. 3665- 3670 ,(2003) , 10.1073/PNAS.0636830100
Maggie Verrall, Unilever consigns manganese catalyst to the back-burner Nature. ,vol. 373, pp. 181- 181 ,(1995) , 10.1038/373181B0
Athina Zouni, Horst-Tobias Witt, Jan Kern, Petra Fromme, Norbert Krauss, Wolfram Saenger, Peter Orth, Crystal structure of photosystem II from Synechococcus elongatus at 3.8 A resolution. Nature. ,vol. 409, pp. 739- 743 ,(2001) , 10.1038/35055589
T. Tzedakis, H. Durliat, M. Comtat, Electrochemical characterization of the {(TPA)Mn(III)O2Mn(IV)(TPA)}2(SO4)3 complex Journal of Electroanalytical Chemistry. ,vol. 421, pp. 187- 194 ,(1997) , 10.1016/S0022-0728(96)04822-X
Alexander Sorokin, Laurent Fraisse, Alain Rabion, Bernard Meunier, Metallophthalocyanine-catalyzed oxidation of catechols by H2O2 and its surrogates Journal of Molecular Catalysis A: Chemical. ,vol. 117, pp. 103- 114 ,(1997) , 10.1016/S1381-1169(96)00415-3