über die Reaktionen von CH3OCl, CF3OCl, CF3OF und CF3OH mit dem supersauren System HF/MF5 (M = As, Sb) Darstellung und Charakterisierung von CH3OCl(H)+MF6− und CF3OCl(H)+MF6−
作者： Rolf Minkwitz , Detlef Konikowski
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摘要: Es wird uber die Darstellung der Chloroxoniumsalze CH3OCl(H)+MF6− und CF3OCl(H)+MF6− durch Protonierung von CH3OCl CF3OCl in dem supersauren System HF/MF5 (M = As, Sb) berichtet. Dagegen lassen sich CF3OF CF3OH bei gleichen Bedingungen nicht protonieren. bildet supersaurer Losung Addukte F2CO · MF5. Die Charakterisierung aller neuen Verbindungen erfolgt NMR- schwingungsspektroskopisch. On the Reactions of CH3OCl, CF3OCl, CF3OF, and with Superacid Sb). Preparation Characterization CF3OCl(H)+MF6− The preparation chlorine oxoniumsalts by protonation superacid solution is described. However have not been protonated under same conditions. In case formation MF5 observed. The novel compounds are characterized nmr- vibrational spectroscopy.
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