Beauty, symmetry, and magnetocaloric effect-four-shell keplerates with 104 lanthanide atoms

作者: Jun-Bo Peng , Xiang-Jian Kong , Qian-Chong Zhang , Martin Orendáč , Jan Prokleška

DOI: 10.1021/JA5107749

关键词:

摘要: The hydrolysis of Ln(ClO 4 ) 3 in the presence of acetate leads to the assembly of the three largest known lanthanide-exclusive cluster complexes, [Nd 104 (ClO 4 ) 6 (CH 3 COO) 60 (μ …

参考文章(29)
H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl, R. E. Smalley, C 60 : Buckminsterfullerene Nature. ,vol. 318, pp. 162- 163 ,(1985) , 10.1038/318162A0
Vitalij K. Pecharsky, Karl A. Gschneidner Jr, Magnetocaloric effect and magnetic refrigeration Journal of Magnetism and Magnetic Materials. ,vol. 200, pp. 44- 56 ,(1999) , 10.1016/S0304-8853(99)00397-2
Q.-F. Sun, J. Iwasa, D. Ogawa, Y. Ishido, S. Sato, T. Ozeki, Y. Sei, K. Yamaguchi, M. Fujita, Self-Assembled M24L48 Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation Science. ,vol. 328, pp. 1144- 1147 ,(2010) , 10.1126/SCIENCE.1188605
Xiang-Jian Kong, La-Sheng Long, Zhiping Zheng, Rong-Bin Huang, Lan-Sun Zheng, Keeping the Ball Rolling: Fullerene-like Molecular Clusters Accounts of Chemical Research. ,vol. 43, pp. 201- 209 ,(2010) , 10.1021/AR900089K
Junfeng Bai, Alexander V Virovets, Manfred Scheer, Synthesis of inorganic fullerene-like molecules. Science. ,vol. 300, pp. 781- 783 ,(2003) , 10.1126/SCIENCE.1081119
Yan-Zhen Zheng, Guo-Jun Zhou, Zhiping Zheng, Richard E. P. Winpenny, Molecule-based magnetic coolers. Chemical Society Reviews. ,vol. 43, pp. 1462- 1475 ,(2014) , 10.1039/C3CS60337G
Li-Xian Chang, Gang Xiong, Li Wang, Peng Cheng, Bin Zhao, A 24-Gd nanocapsule with a large magnetocaloric effect Chemical Communications. ,vol. 49, pp. 1055- 1057 ,(2013) , 10.1039/C2CC35800J
Xiang-Jian Kong, Yan-Ping Ren, La-Sheng Long, Zhiping Zheng, Rong-Bin Huang, Lan-Sun Zheng, A keplerate magnetic cluster featuring an icosidodecahedron of Ni(II) ions encapsulating a dodecahedron of La(III) ions. Journal of the American Chemical Society. ,vol. 129, pp. 7016- 7017 ,(2007) , 10.1021/JA0726198
Christopher E. Anson, Andreas Eichhöfer, Ibrahim Issac, Dieter Fenske, Olaf Fuhr, Paloma Sevillano, Claudia Persau, Dietmar Stalke, Jiatao Zhang, Synthesis and crystal structures of the ligand-stabilized silver chalcogenide clusters [Ag154Se77(dppxy)18], [Ag320(StBu)60S130(dppp)12], [Ag352S128(StC5H11)96], and [Ag490S188(StC5H11)114]. Angewandte Chemie. ,vol. 47, pp. 1326- 1331 ,(2008) , 10.1002/ANIE.200704249
O. Tegus, E. Brück, K. H. J. Buschow, F. R. de Boer, Transition-metal-based magnetic refrigerants for room-temperature applications Nature. ,vol. 415, pp. 150- 152 ,(2002) , 10.1038/415150A