Micro-Drilling of Polymer Tubular Ultramicroelectrode Arrays for Electrochemical Sensors

作者: Jan Kafka , Steen Skaarup , Oliver Geschke , Niels Larsen

DOI: 10.3390/S130506319

关键词:

摘要: We present a reproducible fast prototyping procedure based on micro-drilling to produce homogeneous tubular ultramicroelectrode arrays made from poly(3,4-ethylenedioxythiophene) (PEDOT), conductive polymer. Arrays of O 100 µm electrodes each having height 0.37 ± 0.06 were reproducibly fabricated. The electrode dimensions analyzed by SEM after deposition silver dendrites visualize the electroactive area. electrochemical applicability was demonstrated voltammetric and amperometric detection ferri-/ferrocyanide. Recorded signals in agreement with results finite element modelling system. PEDOT modified prussian blue enable hydrogen peroxide. A linear sensor response for peroxide concentrations 0.1 mM 1 mM.

参考文章(22)
Karel Holub, Christian Amatore, J. Heyrovský, MICROELECTRODES. DEFINITIONS, CHARACTERIZATION, AND APPLICATIONS ,(2000)
Masato Kakihana, Haruko Ikeuchi, Gen P. Satô, Koichi Tokuda, Diffusion current at microdisk electrodes—application to accurate measurement of diffusion coefficients Journal of Electroanalytical Chemistry. ,vol. 117, pp. 201- 211 ,(1981) , 10.1016/S0022-0728(81)80082-4
Sten O. Engblom, Davis K. Cope, Dennis E. Tallman, Diffusion current at the tubular band electrode by the integral equation method Journal of Electroanalytical Chemistry. ,vol. 406, pp. 23- 31 ,(1996) , 10.1016/0022-0728(95)04446-9
Horacio R. Corti, Darío L. Goldfurb, Martin Scalabrini Ortiz, Jorge F. Magallanes, Tubular Band Microelectrode. I. Design and Electrochemical Behavior Electroanalysis. ,vol. 7, pp. 569- 573 ,(1995) , 10.1002/ELAN.1140070612
Laura A. Hutton, Marcio Vidotti, James G. Iacobini, Chris Kelly, Mark E. Newton, Patrick R. Unwin, Julie V. Macpherson, Fabrication and characterization of an all-diamond tubular flow microelectrode for electroanalysis. Analytical Chemistry. ,vol. 83, pp. 5804- 5808 ,(2011) , 10.1021/AC2010247
Thomas Steen Hansen, Keld West, Ole Hassager, Niels B. Larsen, Integration of conducting polymer network in non-conductive polymer substrates Synthetic Metals. ,vol. 156, pp. 1203- 1207 ,(2006) , 10.1016/J.SYNTHMET.2006.08.009
Xing-Jiu Huang, Aoife M. O'Mahony, Richard G. Compton, Microelectrode arrays for electrochemistry: approaches to fabrication. Small. ,vol. 5, pp. 776- 788 ,(2009) , 10.1002/SMLL.200801593
Jahir Orozco, César Fernández-Sánchez, Cecilia Jiménez-Jorquera, Ultramicroelectrode array based sensors: a promising analytical tool for environmental monitoring. Sensors. ,vol. 10, pp. 475- 490 ,(2010) , 10.3390/S100100475
Robert J. Forster, Microelectrodes: new dimensions in electrochemistry Chemical Society Reviews. ,vol. 23, pp. 289- 297 ,(1994) , 10.1039/CS9942300289