Fine Chemicals and their Synthesis; a Chemical Point of View

作者: A. Cybulski , J.A. Moulijn , M.M. Sharma , R.A. Sheldon

DOI: 10.1016/B978-044482202-4/50002-X

关键词:

摘要: A substance that is currently viewed as a bulk chemical classified fine chemical. This chapter provides synoptic view of chemicals and their synthesis. Fine are generally complex, multifunctional molecules, often have low volatility limited thermal stability. implies the processes performed in liquid phase. manufacture involves multi-step syntheses batch-wise multi-purpose equipment. The major characteristic features discussed chapter. domain synthetic organic chemist who traditionally used time honored classical reactions complete disregard atom utilization or efficiency concept root cause waste problem manufacture. Another prime generation use stoichiometric inorganic reagents. specialties rampant with technologies. Hence, catalysis plays pivotal role development clean, environmentally benign generate minimum amounts wastes. Catalytic transformations can be divided on basis catalyst type – homogeneous, heterogeneous enzymatic, conversion. key to more economical reduction number unit operations by judicious process integration.

参考文章(64)
E.A. Gunnewegh, A.J. Hoefnagel, R.S. Downing, H. van Bekkum, ENVIRONMENTALLY FRIENDLY SYNTHESIS OF COUMARIN DERIVATIVES EMPLOYING HETEROGENEOUS CATALYSIS Recueil des Travaux Chimiques des Pays-Bas. ,vol. 115, pp. 226- 230 ,(1996) , 10.1002/RECL.19961150407
Ivan V Kozhevnikov, Fine organic synthesis with the aid of heteropolycompounds Russian Chemical Reviews. ,vol. 62, pp. 473- 491 ,(1993) , 10.1070/RC1993V062N05ABEH000028
Alain Chauvel, Bernard Delmon, Wolfgang F. Hölderich, New catalytic processes developed in Europe during the 1980's Applied Catalysis A-general. ,vol. 115, pp. 173- 217 ,(1994) , 10.1016/0926-860X(94)80353-6
Tomas Hudlicky, Dean A. Frey, Lukasz Koroniak, Christopher D. Claeboe, Larry E. Brammer Jr., Toward a ‘reagent-free’ synthesis Green Chemistry. ,vol. 1, pp. 57- 59 ,(1999) , 10.1039/A901397K
Robert Robinson, LXIII.—A synthesis of tropinone J. Chem. Soc., Trans.. ,vol. 111, pp. 762- 768 ,(1917) , 10.1039/CT9171100762
A. Corma, R.M. Martín-Aranda, Application of solid base catalysts in the preparation of prepolymers by condensation of ketones and malononitrile Applied Catalysis A: General. ,vol. 105, pp. 271- 279 ,(1993) , 10.1016/0926-860X(93)80252-L
Isabel W. C. E. Arends, Roger A. Sheldon, Martin Wallau, Ulf Schuchardt, Oxidative Transformations of Organic Compounds Mediated by Redox Molecular Sieves Angewandte Chemie. ,vol. 36, pp. 1144- 1163 ,(1997) , 10.1002/ANIE.199711441
A.P. Singh, A.K. Pandey, Acetylation of benzene to acetophenone over zeolite catalysts Journal of Molecular Catalysis A: Chemical. ,vol. 123, pp. 141- 147 ,(1997) , 10.1016/S1381-1169(97)00050-2