Performance enhancement of polymer solar cells with high work function CuS modified ITO as anodes

作者: Hongwei Lei , Pingli Qin , Weijun Ke , Yaxiong Guo , Xin Dai

DOI: 10.1016/J.ORGEL.2015.03.051

关键词:

摘要: Abstract In this paper, a thin layer of high work function CuS was introduced to the interface between anode and hole transporting (HTL) modify indium tin oxide (ITO) anode. Modified ITO substrates possess higher function, lower sheet resistance negligible loss in transparency. More importantly, can also benefit for device. Polymer solar cells (PSCs) utilizing modified anodes exhibit significant enhancement power conversion efficiency ( PCE ) air stability compared devices with normal anodes. This modification strategy applies different active systems. Anode-modified poly (3-hexylthiophene) (P3HT) [6,6]-phenyl-C61-butyric acid methyl ester (PC 61 BM) as 3.5%, while poly(4,8-bis(5-(2-ethyl-hexyl)-thiophene-2-yl)-benzo[l,2-b:4,5-b′] dithiophene-alt-alkylcarbonyl-thieno[3,4-b]thiophene) (PBDTTT-C-T) [6,6]-phenyl-C71-butyric 71 system shows 7.4%. As result, provides good compatibility by PSCs achieve better performance.

参考文章(41)
Jaemin Lee, Byung-Jun Jung, Jeong-Ik Lee, Hye Yong Chu, Lee-Mi Do, Hong-Ku Shim, Modification of an ITO anode with a hole-transporting SAM for improved OLED device characteristics Journal of Materials Chemistry. ,vol. 12, pp. 3494- 3498 ,(2002) , 10.1039/B206939C
Weiwei Li, W. S. Christian Roelofs, Mathieu Turbiez, Martijn M. Wienk, René A. J. Janssen, Polymer Solar Cells with Diketopyrrolopyrrole Conjugated Polymers as the Electron Donor and Electron Acceptor Advanced Materials. ,vol. 26, pp. 3304- 3309 ,(2014) , 10.1002/ADMA.201305910
Sayantan Das, Jea-Young Choi, TL Alford, None, P3HT: PC61BM based solar cells employing solution processed copper iodide as the hole transport layer Solar Energy Materials and Solar Cells. ,vol. 133, pp. 255- 259 ,(2015) , 10.1016/J.SOLMAT.2014.11.004
Yugang Sun, Younan Xia, Shape-Controlled Synthesis of Gold and Silver Nanoparticles Science. ,vol. 298, pp. 2176- 2179 ,(2002) , 10.1126/SCIENCE.1077229
Hyo Jung Kim, Jae Hwa Park, Hyun Hwi Lee, Dong Ryeol Lee, Jang-Joo Kim, The effect of Al electrodes on the nanostructure of poly(3-hexylthiophene): Fullerene solar cell blends during thermal annealing Organic Electronics. ,vol. 10, pp. 1505- 1510 ,(2009) , 10.1016/J.ORGEL.2009.08.016
Steven K. Hau, Hin-Lap Yip, Hong Ma, Alex K.-Y. Jen, High performance ambient processed inverted polymer solar cells through interfacial modification with a fullerene self-assembled monolayer Applied Physics Letters. ,vol. 93, pp. 233304- ,(2008) , 10.1063/1.3028094
Ji Hwang Lee, Jong Hwan Park, Jong Soo Kim, Dong Yun Lee, Kilwon Cho, None, High efficiency polymer solar cells with wet deposited plasmonic gold nanodots Organic Electronics. ,vol. 10, pp. 416- 420 ,(2009) , 10.1016/J.ORGEL.2009.01.004
Yan Gao, Hin-Lap Yip, Steven K. Hau, Kevin M. O’Malley, Nam Chul Cho, Hongzheng Chen, Alex K.-Y. Jen, Anode modification of inverted polymer solar cells using graphene oxide Applied Physics Letters. ,vol. 97, pp. 203306- ,(2010) , 10.1063/1.3507388
Qi Xu, Fuzhi Wang, Zhan’ao Tan, Liangjie Li, Shusheng Li, Xuliang Hou, Gang Sun, Xiaohe Tu, Jianhui Hou, Yongfang Li, High-Performance Polymer Solar Cells with Solution-Processed and Environmentally Friendly CuOx Anode Buffer Layer ACS Applied Materials & Interfaces. ,vol. 5, pp. 10658- 10664 ,(2013) , 10.1021/AM402745T
Y. Zhou, C. Fuentes-Hernandez, J. Shim, J. Meyer, A. J. Giordano, H. Li, P. Winget, T. Papadopoulos, H. Cheun, J. Kim, M. Fenoll, A. Dindar, W. Haske, E. Najafabadi, T. M. Khan, H. Sojoudi, S. Barlow, S. Graham, J.-L. Bredas, S. R. Marder, A. Kahn, B. Kippelen, A Universal Method to Produce Low―Work Function Electrodes for Organic Electronics Science. ,vol. 336, pp. 327- 332 ,(2012) , 10.1126/SCIENCE.1218829