Stabilization of lithium superionic conduction phase and enhancement of conductivity of LiBH4 by LiCl addition
作者： Motoaki Matsuo , Hitoshi Takamura , Hideki Maekawa , Hai-Wen Li , Shin-ichi Orimo
DOI: 10.1063/1.3088857
关键词:
摘要: LiBH4 exhibits lithium superionic conduction accompanied by structural transition at around 390 K. Addition of LiCl to drastically affects both the and electrical conductivity: Transition from low-temperature (LT) high-temperature (HT) phases in is observed 370 K upon heating HT phase can be retained 350–330 cooling. Further, conductivity LT more than one or two orders magnitude higher that pure LiBH4. These properties could attributed dissolution into LiBH4, suggested situ x-ray diffraction measurement.
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