Thermal removal of PCDD/Fs from medical waste incineration fly ash--effect of temperature and nitrogen flow rate.

作者: Hai-long Wu , Sheng-yong Lu , Jian-hua Yan , Xiao-dong Li , Tong Chen

DOI: 10.1016/J.CHEMOSPHERE.2011.02.015

关键词:

摘要: The fly ash used in this study was collected from a bag filter medical waste rotary kiln incineration system, using lime and activated carbon injection followed by their collection as mixed ash. Experiments were conducted on quartz tube, heated laboratory-scale horizontal tube furnace, order to the effect of temperature nitrogen flow rate removal PCDD/Fs. Results indicated that PCDD/Fs mostly removed desorbed very little into flue gas under thermal treatment especially when heating higher than 350 °C, dechlorination destruction reactions took important part However, terms rate, 4 cm s(-1), efficiency decreased dramatically main contributors P(5)CDF, H(6)CDF H(7)CDF gas, with enhanced rate.

参考文章(28)
Jeong-Eun Oh, Kyung-Tae Lee, Jae-Whan Lee, Yoon-Seok Chang, The evaluation of PCDD/Fs from various Korean incinerators Chemosphere. ,vol. 38, pp. 2097- 2108 ,(1999) , 10.1016/S0045-6535(98)00419-6
Lisa Lundin, Stellan Marklund, Distribution of mono to octa-chlorinated PCDD/Fs in fly ash from a municipal solid-waste incinerator. Environmental Science & Technology. ,vol. 42, pp. 1245- 1250 ,(2008) , 10.1021/ES0717919
Lisa Lundin, Stellan Marklund, Thermal Degradation of PCDD/F in Municipal Solid Waste Ashes in Sealed Glass Ampules Environmental Science & Technology. ,vol. 39, pp. 3872- 3877 ,(2005) , 10.1021/ES0485513
J YAN, Z PENG, S LU, X LI, M NI, K CEN, H DAI, Degradation of PCDD/Fs by mechanochemical treatment of fly ash from medical waste incineration Journal of Hazardous Materials. ,vol. 147, pp. 652- 657 ,(2007) , 10.1016/J.JHAZMAT.2007.02.073
Yongjin Kim, Donghoon Lee, Solubility enhancement of PCDD/F in the presence of dissolved humic matter Journal of Hazardous Materials. ,vol. 91, pp. 113- 127 ,(2002) , 10.1016/S0304-3894(01)00364-8
T Chen, JH Yan, SY Lu, XD Li, YL Gu, HF Dai, MJ Ni, KF Cen, None, Characteristic of polychlorinated dibenzo-p-dioxins and dibenzofurans in fly ash from incinerators in china. Journal of Hazardous Materials. ,vol. 150, pp. 510- 514 ,(2008) , 10.1016/J.JHAZMAT.2007.04.131
Jae-Yong Ryu, James A. Mulholland, Do Hyong Kim, Masao Takeuchi, Homologue and Isomer Patterns of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from Phenol Precursors: Comparison with Municipal Waste Incinerator Data Environmental Science & Technology. ,vol. 39, pp. 4398- 4406 ,(2005) , 10.1021/ES048224V
B. R. Stanmore, C. Clunies-Ross, An Empirical Model for the De Novo Formation of PCDD/F in Medical Waste Incinerators Environmental Science & Technology. ,vol. 34, pp. 4538- 4544 ,(2000) , 10.1021/ES001160D
B.R Stanmore, The formation of dioxins in combustion systems Combustion and Flame. ,vol. 136, pp. 398- 427 ,(2004) , 10.1016/J.COMBUSTFLAME.2003.11.004