Effect of halogen purification and heat treatment on thermal conductivity of high porosity carbon/carbon composite thermal insulation

作者: R. I. Baxter , N. Iwashita , Y. Sawada

DOI: 10.1023/A:1004770429911

关键词:

摘要: Thermal conductivity of a highly porous carbon/carbon composite, known as carbon bonded fiber (CBCF) and used thermal insulation, was measured related to the structure investigated by optical microscopy, x-ray diffraction Raman spectroscopy. It found that halogen purification CBCF, involves heat treatment in chlorine atmosphere, did not result greater extent structural development than at same temperature for time inert atmosphere (unpurified sample). The both purified unpurified, increase with range 1000°C 2200°C. experimental values were good agreement those calculated from model indicated CBCF solid transfer dominant, compared radiation transfer, even matrix be relatively graphitic stress orientation on carbonization observed along length it tentatively suggested may contribute effective axial fibers.

参考文章(15)
Gene Dresselhaus, Harris A. Goldberg, Ko Sugihara, Ian L. Spain, Mildred S. Dresselhaus, Graphite Fibers and Filaments ,(1988)
T. G. Godfrey, D. L. McElroy, Z. L. Ardary, Thermal Conductivity of Oriented Fibrous Carbon Insulation from 300 to 1300°K in Nitrogen and Argon at One Atmosphere Nuclear Technology. ,vol. 22, pp. 94- 107 ,(1974) , 10.13182/NT74-A16278
Robert D. Cowan, Pulse Method of Measuring Thermal Diffusivity at High Temperatures Journal of Applied Physics. ,vol. 34, pp. 926- 927 ,(1963) , 10.1063/1.1729564
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
Cho Yen Ho, Thermal Conductivity of the Elements Journal of Physical and Chemical Reference Data. ,vol. 1, pp. 279- 421 ,(1972) , 10.1063/1.3253100
P.M. Adams, H.A. Katzman, G.S. Rellick, G.W. Stupian, Characterization of high thermal conductivity carbon fibers and a self-reinforced graphite panel Carbon. ,vol. 36, pp. 233- 245 ,(1998) , 10.1016/S0008-6223(97)00189-9
I.J. Davies, R.D. Rawlings, Mechanical properties in compression of low density carbon/carbon composites Composites. ,vol. 25, pp. 229- 236 ,(1994) , 10.1016/0010-4361(94)90021-3
Ian J. Davies, Rees D. Rawlings, Mechanical properties in compression of CVI-densified porous carbon/carbon composite Composites Science and Technology. ,vol. 59, pp. 97- 104 ,(1999) , 10.1016/S0266-3538(98)00059-1