Molecular translational-rovibronic hamiltonian. I. Non-linear molecules
作者： Reza Islampour , Michael Kasha
DOI: 10.1016/0301-0104(83)80008-1
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摘要: Abstract The translational-rovibronic hamiltonian for a non-linear polyatomic molecule is derived by using the Schrodinger equation in tensor form and employing Eckart conditions (determining nuclear-framework rotational variables). present derivation unified comprehensive one quantum-mechanical pathway contrasts with fragmentary previous derivations via classical-intermediate path. method presented affords firm conceptual picture of nature transformation origin coupling terms, avoids mathematical complexities their residue obscurity. correct total angular momentum operators also quantum mechanically.
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