Electrochemical polymerization of EDOT modified Phthalocyanines and their applications as electrochromic materials with green coloration, and strong absorption in the Near-IR
作者： Claudia Solis , Estefanía Baigorria , María Elisa Milanesio , Gustavo Morales , Edgardo N. Durantini
DOI: 10.1016/J.ELECTACTA.2016.07.086
关键词:
摘要: Abstract Electropolymerization by cyclic voltammetry of both Cu and Zn EDOT modified phthalocyanines is described. Polymeric films were successfully formed on Pt, ITO, Pt containing a previously deposited layer PEDOT. Based electrochemical spectroelectrochemical studies, possible polymerization mechanism polymer structure are proposed. The showed green coloration in the reduced state grey also very broad band that extends to NIR zone fully oxidized state. Optical contrast ratios 24% at 650 nm, 60% 1050 nm achieved, with fast switching times. A window-type device was constructed, demonstrating applications these electrochromic materials smart windows, which could help control light visible heat flux because their strong absorption range.
sci-hub.se 参考文章(64)
Dei-Wei Chou, Kan-Lin Chen, Chien-Jung Huang, Yao-Jen Tsao, Wen-Ray Chen, Teen-Hang Meen, Efficient small-molecule organic solar cells incorporating a doped buffer layer Thin Solid Films. ,vol. 536, pp. 235- 239 ,(2013) , 10.1016/J.TSF.2013.04.008
Hasan Kutay Yıldız, Sibel Eken Korkut, Atıf Koca, M. Kasım Şener, 3,4-Ethylenedioxythiophene substituted phthalocyanines Synthetic Metals. ,vol. 161, pp. 1946- 1952 ,(2011) , 10.1016/J.SYNTHMET.2011.06.040
Inho Kim, Hanna M. Haverinen, Jian Li, Ghassan E. Jabbour, Enhanced power conversion efficiency of p-i-n type organic solar cells by employing a p-layer of palladium phthalocyanine Applied Physics Letters. ,vol. 97, pp. 203301- ,(2010) , 10.1063/1.3507387
Kalle Lintinen, Linda Storbacka, Alexander Efimov, Antti Tolkki, Nikolai Tkachenko, Helge Lemmetyinen, Photocurrent generation in fullerene–phthalocyanine composite by in situ cationic polymerization Solar Energy Materials and Solar Cells. ,vol. 95, pp. 909- 916 ,(2011) , 10.1016/J.SOLMAT.2010.11.018
Marcel Bouvet, Pierre Gaudillat, Jean-Moïse Suisse, Phthalocyanine-based hybrid materials for chemosensing Journal of Porphyrins and Phthalocyanines. ,vol. 17, pp. 913- 919 ,(2013) , 10.1142/S1088424613300073
Mine Ince, Jun-Ho Yum, Yongjoo Kim, Simon Mathew, Michael Grätzel, Tomás Torres, Mohammad K. Nazeeruddin, Molecular Engineering of Phthalocyanine Sensitizers for Dye-Sensitized Solar Cells Journal of Physical Chemistry C. ,vol. 118, pp. 17166- 17170 ,(2014) , 10.1021/JP502447Y
Palanisamy Kalimuthu, Arumugam Sivanesan, S Abraham John, None, Fabrication of optochemical and electrochemical sensors using thin films of porphyrin and phthalocyanine derivatives Journal of Chemical Sciences. ,vol. 124, pp. 1315- 1325 ,(2012) , 10.1007/S12039-012-0330-5
Volkan Çakır, Halit Kantekin, Zekeriya Bıyıklıoğlu, Atıf Koca, New electropolymerizable metal-free, metallophthalocyanines and their electrochemical, spectroelectrochemical studies Journal of Organometallic Chemistry. ,vol. 768, pp. 28- 35 ,(2014) , 10.1016/J.JORGANCHEM.2014.06.006
Wallace C. H. Choy, Wai Kin Chan, Yuping Yuan, Recent Advances in Transition Metal Complexes and Light-Management Engineering in Organic Optoelectronic Devices Advanced Materials. ,vol. 26, pp. 5368- 5399 ,(2014) , 10.1002/ADMA.201306133
Tilia Patois, Jean-Baptiste Sanchez, Franck Berger, Patrick Fievet, Olivier Segut, Virginie Moutarlier, Marcel Bouvet, Boris Lakard, Elaboration of ammonia gas sensors based on electrodeposited polypyrrole--cobalt phthalocyanine hybrid films. Talanta. ,vol. 117, pp. 45- 54 ,(2013) , 10.1016/J.TALANTA.2013.08.047