Molecular Properties and Reaction Mechanism of Multicopper Oxidases Related to Their Use in Biofuel Cells
作者： Edward I. Solomon , Christian H. Kjaergaard , David E. Heppner
DOI: 10.1002/9781118899076.CH8
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摘要: The multicopper oxidases (MCOs) are a ubiquitous family of proteins that carry out four single-electron oxidations substrates coupled to the four-electron reduction dioxygen water (Eq. 8.1) [1]. These enzymes diverse set oxidation reactions and based on their reactivity can be placed into one two categories: those oxidize organic molecules (organic oxidases) metal ions (metalloxidases) (Table 8.1). metalloxidases specific toward substrate, while generally exhibit broad substrate specificity:
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