Density and phase equilibrium for ice and structure I hydrates using the Gibbs–Helmholtz constrained equation of state
作者： Heath Henley , Edward Thomas , Angelo Lucia
DOI: 10.1016/J.CHERD.2014.06.011
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摘要: a b s t r c A new, rigorous framework centered around the multi-scale GHC equation of state is presented for predicting bulk density and phase equilibrium light gas–water mixtures at conditions where hexagonal ice structure I hydrate phases can exist. The novel aspects this new include (1) use internal energies departure empty respectively to determine densities, (2) contributions standard fugacity water in from lattice structure, (3) computation these structural compressibility factors EOS parameters alone, (4) direct calculation gas occupancy equilibrium. Numerical results densities systems involving and/or hydrates predicted by GHC-based are compared predictions other equations state, correlations, experimental data available. Results show that accurately predicts as well methane–water CO2–water mixtures. © 2014 Institution Chemical Engineers. Published Elsevier B.V. All rights reserved.
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sci-hub.se 参考文章(50)
M.D. Jager, A.L. Ballard, E.D. Sloan, The next generation of hydrate prediction: II. Dedicated aqueous phase fugacity model for hydrate prediction Fluid Phase Equilibria. ,vol. 211, pp. 85- 107 ,(2003) , 10.1016/S0378-3812(03)00155-9
Georgios M Kontogeorgis, Georgios K Folas, Thermodynamic Models for Industrial Applications: From Classical and Advanced Mixing Rules to Association Theories ,(2010)
Walter G. Chapman, George Jackson, Keith E. Gubbins, Phase equilibria of associating fluids Molecular Physics. ,vol. 65, pp. 1057- 1079 ,(2006) , 10.1080/00268978800101601
Barnett F. Dodge, Chemical engineering thermodynamics McGraw-Hill. ,(1944)
Rainer Feistel, Wolfgang Wagner, A New Equation of State for H2O Ice Ih Journal of Physical and Chemical Reference Data. ,vol. 35, pp. 1021- 1047 ,(2006) , 10.1063/1.2183324
G Brewer, PG, Friederich, ET Peltzer, FM Orr, Direct Experiments on the Ocean Disposal of Fossil Fuel CO2 Science. ,vol. 284, pp. 943- 945 ,(1999) , 10.1126/SCIENCE.284.5416.943
Phillip Servio, Peter Englezos, Measurement of Dissolved Methane in Water in Equilibrium with Its Hydrate Journal of Chemical & Engineering Data. ,vol. 47, pp. 87- 90 ,(2002) , 10.1021/JE0102255
W. Wagner, A. Pruß, The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use Journal of Physical and Chemical Reference Data. ,vol. 31, pp. 387- 535 ,(2002) , 10.1063/1.1461829
Antonin Chapoy, Amir H. Mohammadi, Dominique Richon, Bahman Tohidi, Gas solubility measurement and modeling for methane–water and methane–ethane–n-butane–water systems at low temperature conditions Fluid Phase Equilibria. ,vol. 220, pp. 113- 121 ,(2004) , 10.1016/J.FLUID.2004.02.010
E. G. Hammerschmidt, Formation of Gas Hydrates in Natural Gas Transmission Lines Industrial & Engineering Chemistry. ,vol. 26, pp. 851- 855 ,(1934) , 10.1021/IE50296A010