Solid state ionics. High ionic conductivity solid in silver halide-silver sulphate system

摘要: The ionic conductivities and phase diagrams of AgI-Ag2SO4, AgCl-Ag2SO4 AgBr-Ag2SO4 systems have been studied with the help electrical conductivity, transport number, DTA X-ray studies. In AgI-Ag2SO4 system, solid solution α-AgI Ag2SO4 was quenched to room temperature high conductivity 5·0×10−2 (ohm. cm)−1 at 1·3×10−3 −78°C. stable −20°C, but gradually decomposed toβ-AgI andβ-Ag2SO4 temperature. number silver ion in this about 1·0. systems, order 10−4 10−6